N-(3-溴-2-甲基苯基)乙酰胺合成路线 （共 3 条）
反应条件
in ethyl acetate
T=85°C; 0.666667 h;
参考文献
Zheng, Nan; Anderson, Kevin W.; Huang, Xiaohua; Nguyen, Hanh Nho; Buchwald, Stephen L.
Angewandte Chemie - International Edition, 2007 , vol. 46, # 39 p. 7509 - 7512
反应条件
hydrogenchloride; tin
und Behandeln des erhaltenen 2-Brom-3-methyl-anilins mit Acetanhydrid;
参考文献
Ukai
Yakugaku Zasshi, 1931 , vol. 51, p. 542,571; dtsch. Ref. S. 73, 76
Chem.Abstr., 1931 , p. 5427
反应条件
1: 63 percent / tri-o-tolylphosphine, triethylamine / palladium(II) acetate / acetonitrile / 24 h / 120 °C / 22800 Torr
2: 49 percent / oxygen / palladium(II) chloride, copper(I) chloride / 1,2-dimethoxy-ethane / 760 Torr
View Scheme
参考文献
Kasahara, Akira; Izumi, Taeko; Murakami, Satoshi; Miyamoto, Kazuhiro; Hino, Toshimi
Journal of Heterocyclic Chemistry, 1989 , vol. 26, p. 1405 - 1413
