1-(4-甲烷磺酰基-苯基)-2-苯基-1,2-乙二酮合成路线 （共 11 条）
反应条件
formic acid; methanesulfonic acid; dimethyl sulfoxide; hydrogen bromide
T=105 - 110°C; 15 h;
参考文献
Wan, Zhonghui; Jones, Chauncey D.; Mitchell, David; Pu, John Y.; Zhang, Tony Y.
Journal of Organic Chemistry, 2006 , vol. 71, # 2 p. 826 - 828
反应条件
potassium permanganate; acetic anhydride
T=0°C;
参考文献
Barta, Thomas E.; Stealey, Michael A.; Collins, Paul W.; Weier, Richard M.
Bioorganic and Medicinal Chemistry Letters, 1998 , vol. 8, # 24 p. 3443 - 3448
反应条件
1: H2O2; glacial acetic acid / 50 - 60 °C
2: SeO2 / dioxane; H2O / Heating
View Scheme
参考文献
Singh, Sunil K.; Saibaba; Ravikumar; Rudrawar, Santosh V.; Daga, Pankaj; Rao, C. Seshagiri; Akhila; Hegde; Rao, Y. Koteswar
Bioorganic and Medicinal Chemistry, 2004 , vol. 12, # 8 p. 1881 - 1893
反应条件
selenium(IV) oxide; acetic anhydride
参考文献
Coan et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 60,62, 63
反应条件
1: AlCl3 / CH2Cl2 / 0 - 20 °C
2: H2O2; glacial acetic acid / 50 - 60 °C
3: SeO2 / dioxane; H2O / Heating
View Scheme
参考文献
Singh, Sunil K.; Saibaba; Ravikumar; Rudrawar, Santosh V.; Daga, Pankaj; Rao, C. Seshagiri; Akhila; Hegde; Rao, Y. Koteswar
Bioorganic and Medicinal Chemistry, 2004 , vol. 12, # 8 p. 1881 - 1893
反应条件
1: AlCl3 / CH2Cl2 / 0 - 20 °C
2: H2O2; glacial acetic acid / 50 - 60 °C
3: SeO2 / dioxane; H2O / Heating
View Scheme
参考文献
Singh, Sunil K.; Saibaba; Ravikumar; Rudrawar, Santosh V.; Daga, Pankaj; Rao, C. Seshagiri; Akhila; Hegde; Rao, Y. Koteswar
Bioorganic and Medicinal Chemistry, 2004 , vol. 12, # 8 p. 1881 - 1893
反应条件
dihydrogen peroxide; acetic acid
T=50°C; 5 h;
参考文献
Singh, Sunil K.; Saibaba; Ravikumar; Rudrawar, Santosh V.; Daga, Pankaj; Rao, C. Seshagiri; Akhila; Hegde; Rao, Y. Koteswar
Bioorganic and Medicinal Chemistry, 2004 , vol. 12, # 8 p. 1881 - 1893
反应条件
1: 88 percent / LiOEt / ethanol / Heating
2: 72 percent / KMnO4, Ac2O / 0 °C
View Scheme
参考文献
Barta, Thomas E.; Stealey, Michael A.; Collins, Paul W.; Weier, Richard M.
Bioorganic and Medicinal Chemistry Letters, 1998 , vol. 8, # 24 p. 3443 - 3448
反应条件
1: 85 percent / toluene / Heating
2: 88 percent / LiOEt / ethanol / Heating
3: 72 percent / KMnO4, Ac2O / 0 °C
View Scheme
参考文献
Barta, Thomas E.; Stealey, Michael A.; Collins, Paul W.; Weier, Richard M.
Bioorganic and Medicinal Chemistry Letters, 1998 , vol. 8, # 24 p. 3443 - 3448
反应条件
1: 1.) LiOEt, 2.) OxoneTM / 1.) EtOH, RT, 2.5 h, 2.) aq. MeOH, a) 0 deg C, 15 min, b) RT, 1.5 h
2: 72 percent / KMnO4, Ac2O / 0 °C
View Scheme
参考文献
Barta, Thomas E.; Stealey, Michael A.; Collins, Paul W.; Weier, Richard M.
Bioorganic and Medicinal Chemistry Letters, 1998 , vol. 8, # 24 p. 3443 - 3448
