1: Agrocybe aegerita aromatic peroxygenase; dihydrogen peroxide / acetonitrile / pH 7 / aq. phosphate buffer; Enzymatic reaction 2: (18)O labeled hydrogen peroxide; Agrocybe aegerita aromatic peroxygenase / acetonitrile / pH 7 / aq. phosphate buffer; Enzymatic reaction View Scheme

(18)O labeled hydrogen peroxide; Agrocybe aegerita aromatic peroxygenase in acetonitrile pH=7; aq. phosphate bufferEnzymatic reaction;

1: toluene-4-sulfonic acid; copper(II) sulfate / benzene / 52 h / 20 °C / |Inert atmosphere 2: H218O / acetonitrile / 20 °C / |Irradiation View Scheme

(18)O labeled hydrogen peroxide; Agrocybe aegerita aromatic peroxygenase in acetonitrile pH=7; aq. phosphate bufferEnzymatic reaction;

titanium dioxide; oxygen Molecular sieveSealed tubeUV-irradiation;

oxygen in toluene Kinetics; byproducts: dibenzyl, benzyl cyanide; stirring of the Ni compd. in toluene under O2 under atmospheric pressure for 2000-5000 sec.; identification of the products by GC analysis and IR;

[(hydrotris(3,5-diphenylpyrazole-1-yl)borate)-FeII(benzilate)]; (18)O2

暂无反应条件数据

1: N,N-(dimethylamino)-methylphenylsulfoxonium tetrafluoroborate With sodium hexamethyldisilazane in tetrahydrofuran T=-78°C; 0.75 h; Inert atmosphere; 2: 18O-benzaldehyde in tetrahydrofuran T=-78°C; 1.5 h; Inert atmosphere; 3: isobutyl phenyl ketene in tetrahydrofuran T=-78 - 20°C; Inert atmosphere; diastereoselective reaction;