1,3-二羟基-4-甲基-9H-氧杂蒽-9-酮合成路线 (共 7 条)
反应条件
1: 74 percent / K2CO3 / dimethylformamide / 1 h / Heating
2: 88 percent / POCl3 / CH2Cl2 / Ambient temperature
3: 90 percent / Zn-amalgam, 4 N aq. HCl / dioxane / 2 h / Heating
4: H2 / 10percent Pd/C / ethyl acetate / 0.25 h / Ambient temperature
5: pyridine / 2 h / Heating
6: 68 percent / CrO3, water / acetic acid / 4 h / Ambient temperature
7: aq. KOH / 4 h / Heating
View Scheme
参考文献
Pillai; Naiksatam; Johnson; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 5 p. 717 - 723
反应条件
1: 88 percent / POCl3 / CH2Cl2 / Ambient temperature
2: 90 percent / Zn-amalgam, 4 N aq. HCl / dioxane / 2 h / Heating
3: H2 / 10percent Pd/C / ethyl acetate / 0.25 h / Ambient temperature
4: pyridine / 2 h / Heating
5: 68 percent / CrO3, water / acetic acid / 4 h / Ambient temperature
6: aq. KOH / 4 h / Heating
View Scheme
参考文献
Pillai; Naiksatam; Johnson; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 5 p. 717 - 723
反应条件
1: H2 / 10percent Pd/C / ethyl acetate / 0.25 h / Ambient temperature
2: pyridine / 2 h / Heating
3: 68 percent / CrO3, water / acetic acid / 4 h / Ambient temperature
4: aq. KOH / 4 h / Heating
View Scheme
参考文献
Pillai; Naiksatam; Johnson; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 5 p. 717 - 723
反应条件
1: 90 percent / Zn-amalgam, 4 N aq. HCl / dioxane / 2 h / Heating
2: H2 / 10percent Pd/C / ethyl acetate / 0.25 h / Ambient temperature
3: pyridine / 2 h / Heating
4: 68 percent / CrO3, water / acetic acid / 4 h / Ambient temperature
5: aq. KOH / 4 h / Heating
View Scheme
参考文献
Pillai; Naiksatam; Johnson; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 5 p. 717 - 723
反应条件
1: pyridine / 2 h / Heating
2: 68 percent / CrO3, water / acetic acid / 4 h / Ambient temperature
3: aq. KOH / 4 h / Heating
View Scheme
参考文献
Pillai; Naiksatam; Johnson; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 5 p. 717 - 723
反应条件
1: 68 percent / CrO3, water / acetic acid / 4 h / Ambient temperature
2: aq. KOH / 4 h / Heating
View Scheme
参考文献
Pillai; Naiksatam; Johnson; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 5 p. 717 - 723
反应条件
potassium hydroxide
4 h; Heating;
参考文献
Pillai; Naiksatam; Johnson; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 5 p. 717 - 723