反应条件
n-butyllithium in diethyl ether; hexane n-BuLi in 2.5 M hexane soln. was added to ethereal soln. of C6F4H between -70 and -75 °C, 1.5 equiv. of cold (-70 °C) B(OMe)3 soln. was added in ether, mixt. was kept for 1 h below -60 °C, warmedup to 15-18 °C within 1 h; hydrolysis with 10 percent HCl, org. layer was sepd., aq. layer was twice extd. with ether, extracts were combined, dried with MgSO4, evapd. under vac., recrystn. from toluene, elem. anal.;
参考文献
Frohn; Adonin; Bardin; Starichenko
Zeitschrift fur Anorganische und Allgemeine Chemie, 2002 , vol. 628, # 13 p. 2827 - 2833
