P-(2-甲基苯基)-亚膦二氯化物合成路线 （共 8 条）
参考文献
Michaelis; Paneck
Justus Liebigs Annalen der Chemie, 1882 , vol. 212, p. 203
参考文献
Michaelis; Paneck
Justus Liebigs Annalen der Chemie, 1882 , vol. 212, p. 203
反应条件
1: in tetrahydrofuran
T=-78 - 20°C; 1.5 h;
2: With hydrogenchloride in diethyl ether
T=20°C;
参考文献
CELTIC CATALYSTS LIMITED
Patent: WO2008/117054 A2, 2008 ;
Location in patent: Page/Page column 27-28 ;
反应条件
1.1: Mg; 1,2-dibromoethane / diethyl ether / 1 h / Heating
1.2: diethyl ether / 1 h / 20 °C
2.1: HCl / diethyl ether / 3 h
View Scheme
参考文献
Howell, James A. S.; Fey, Natalie; Lovatt, Jonathan D.; Yates, Paul C.; McArdle, Patrick; Cunningham, Desmond; Sadeh, Einat; Gottlieb, Hugo E.; Goldschmidt, Zeev; Hursthouse, Michael B.; Light, Mark E.
Journal of the Chemical Society - Dalton Transactions, 1999 , # 17 p. 3015 - 3028
参考文献
Hoechst Aktiengesellschaft
Patent: US4632995 A1, 1986 ;
反应条件
phosphorus trichoride
T=45°C; UV-irradiation;
参考文献
Borovinskii; Krivchun; Ionin
Russian Journal of General Chemistry, 2003 , vol. 73, # 5 p. 825 - 826
反应条件
phosphorus trichoride
T=180 - 190°C;
参考文献
Michaelis; Paneck
Justus Liebigs Annalen der Chemie, 1882 , vol. 212, p. 203
Full Text Show Details
Michaelis
Justus Liebigs Annalen der Chemie, 1896 , vol. 293, p. 292
反应条件
hydrogenchloride in diethyl ether
Chlorination; 3 h;
参考文献
Howell, James A. S.; Fey, Natalie; Lovatt, Jonathan D.; Yates, Paul C.; McArdle, Patrick; Cunningham, Desmond; Sadeh, Einat; Gottlieb, Hugo E.; Goldschmidt, Zeev; Hursthouse, Michael B.; Light, Mark E.
Journal of the Chemical Society - Dalton Transactions, 1999 , # 17 p. 3015 - 3028
