2,3-二氢-1H-茚-5-硫氢化物合成路线 （共 9 条）
反应条件
1: 1) conc. H2SO4, 2) PCl5 / 1) 20 deg C, 2) ligroin
2: LiAlH4 / tetrahydrofuran / Heating
View Scheme
参考文献
Bock, Hans; Rittmeyer, Peter
Phosphorus, Sulfur and Silicon and the Related Elements, 1992 , vol. 68, # 1-4 p. 261 - 292
反应条件
1: H2 / Pd-C / ethanol / Ambient temperature
2: (i) (diazotization), (ii) EtOCS2K, H2O, (iii) LiAlH4, Et2O
View Scheme
参考文献
Pailer,M.; Gruenhaus,H.
Monatshefte fuer Chemie, 1974 , vol. 105, p. 1362 - 1373
参考文献
Cagniant
Bulletin de la Societe Chimique de France, 1950 , p. 28,31
反应条件
(i) (diazotization), (ii) EtOCS2K, H2O, (iii) LiAlH4, Et2O; Multistep reaction;
参考文献
Pailer,M.; Gruenhaus,H.
Monatshefte fuer Chemie, 1974 , vol. 105, p. 1362 - 1373
反应条件
1: (i) aq. KOH, (ii) Cu
2: Li<AlH2(OCH2CH2OMe)2> / benzene
3: SOCl2, Py
View Scheme
参考文献
Cervena; Svatek; Metysova; Protiva
Collection of Czechoslovak Chemical Communications, 1974 , vol. 39, # 12 p. 3733 - 3740
反应条件
1: (i) aq. KOH, (ii) Cu
2: Li<AlH2(OCH2CH2OMe)2> / benzene
3: SOCl2, Py
4: aq. ethanol
5: aq. KOH / ethanol
View Scheme
参考文献
Cervena; Svatek; Metysova; Protiva
Collection of Czechoslovak Chemical Communications, 1974 , vol. 39, # 12 p. 3733 - 3740
反应条件
1: (i) aq. KOH, (ii) Cu
2: Li<AlH2(OCH2CH2OMe)2> / benzene
View Scheme
参考文献
Cervena; Svatek; Metysova; Protiva
Collection of Czechoslovak Chemical Communications, 1974 , vol. 39, # 12 p. 3733 - 3740
反应条件
(i) aq. KOH, (ii) Cu; Multistep reaction;
参考文献
Cervena; Svatek; Metysova; Protiva
Collection of Czechoslovak Chemical Communications, 1974 , vol. 39, # 12 p. 3733 - 3740
反应条件
1: (i) aq. KOH, (ii) Cu
2: Li<AlH2(OCH2CH2OMe)2> / benzene
3: SOCl2, Py
4: aq. ethanol
View Scheme
参考文献
Cervena; Svatek; Metysova; Protiva
Collection of Czechoslovak Chemical Communications, 1974 , vol. 39, # 12 p. 3733 - 3740
