in benzene Sn{N(Si(CH3)3)2}2 and Re2{P(CH3)2C6H5}*8H in benzene at 25°C for some days;
参考文献
Westerberg, D. Eric; Sutherland, Bruce R.; Huffman, John C.; Caulton, Kenneth G.
Journal of the American Chemical Society, 1988 , vol. 110, p. 1642 - 1643
in hexane byproducts: ((CH3)3Si)2NH, (CH3)3SiOSi(CH3)3, (CH3)3SiNCS; (Ar); soln. of tin complex in hexane was placed in bomb at -100°C, OCS was added, stirred and warmed to 25°C, stirred overnight; cooled to -78°C excess OCS was removed in vac., filtered, washed with pentane, crystal were obtained from filtrate, elem. anal.;
参考文献
Stewart, Constantine A.; Dickie, Diane A.; Parkes, Marie V.; Saria, Josephat A.; Kemp, Richard A.
Inorganic Chemistry, 2010 , vol. 49, # 23 p. 11133 - 11141
in hexane (inert atmosphere, Schlenk technique); Sn-compd. is dissolved in hexane, solid H2NBMes2 is added slowly at room temp., soln. is refluxed for 1 h and then cooled; volatiles are removed under reduced pressure, residue is redissolved in hexane, filtn., reduction of volume, crystn.;
in neat (no solvent) (inert atmosphere, Schlenk technique); educts are heated together at 50°C for 5 min; HN(SiMe3)2 is removed under reduced pressure, residue is recrystd. from warm hexane;
