5-溴-1,2-二氢-6-碘苊合成路线 （共 3 条）
反应条件
1: With n-butyllithium in diethyl ether; hexane
T=-78°C;
2: With iodine in diethyl ether; hexane
T=-10 - 20°C;
参考文献
Aschenbach, Lara K.; Knight, Fergus R.; Randall, Rebecca A. M.; Cordes, David B.; Baggott, Alex; Buehl, Michael; Slawin, Alexandra M. Z.; Woollins, J. Derek
Dalton Transactions, 2012 , vol. 41, # 11 p. 3141 - 3153
反应条件
1.1: n-butyllithium / diethyl ether; hexane / -78 °C
1.2: -78 °C
2.1: n-butyllithium / diethyl ether; hexane / -78 °C
2.2: -10 - 20 °C
View Scheme
参考文献
Aschenbach, Lara K.; Knight, Fergus R.; Randall, Rebecca A. M.; Cordes, David B.; Baggott, Alex; Buehl, Michael; Slawin, Alexandra M. Z.; Woollins, J. Derek
Dalton Transactions, 2012 , vol. 41, # 11 p. 3141 - 3153
反应条件
(i) aq. H2SO4, NaNO2, (ii) aq. KI, (iii) (heating); Multistep reaction;
参考文献
Karishin,A.P.; Kustol,D.M.
J. Gen. Chem. USSR (Engl. Transl.), 1964 , vol. 34, # 4 p. 1292 - 1294,1291 - 1293
