5-甲基己基-2-丁烯酸合成路线 （共 30 条）
反应条件
1: LiAlH4 / diethyl ether 2: (i) TsCl, Py, (ii) LiBr, DMF 3: nBu3SnH, AIBN / 80 °C View Scheme
参考文献
Julia,M. et al.
Tetrahedron, 1975 , vol. 31, p. 1737 - 1744
参考文献
Ansell; Brown
Journal of the Chemical Society, 1958 , p. 2955,2959
反应条件
1: diethyl ether
2: diethyl ether / Behandeln des Reaktionsprodukts mit Schwefelsaeure enthaltendem Aethanol
View Scheme
参考文献
Kappeler et al.
Helvetica Chimica Acta, 1954 , vol. 37, p. 957,962
参考文献
Kappeler et al.
Helvetica Chimica Acta, 1954 , vol. 37, p. 957,962
反应条件
1: LiAlH4
2: PBr3, Py / pentane
3: (i) Mg, Et2O, (ii) /BRN= 1209228/
View Scheme
参考文献
Johnson,W.S.; Owyang,R.
Journal of the American Chemical Society, 1964 , vol. 86, p. 5593 - 5598
反应条件
1: diethyl ether
2: diethyl ether / Behandeln des Reaktionsprodukts mit Schwefelsaeure enthaltendem Aethanol
3: lithium alanate; diethyl ether
View Scheme
参考文献
Kappeler et al.
Helvetica Chimica Acta, 1954 , vol. 37, p. 957,962
反应条件
1: LiAlH4
2: PBr3, Py / pentane
3: (i) Mg, Et2O, (ii) /BRN= 1209228/
4: tetrahydrofuran
5: HCO2Na, HCO2H
View Scheme
参考文献
Johnson,W.S.; Owyang,R.
Journal of the American Chemical Society, 1964 , vol. 86, p. 5593 - 5598
反应条件
1: LiAlH4
2: PBr3, Py / pentane
3: (i) Mg, Et2O, (ii) /BRN= 1209228/
4: tetrahydrofuran
5: HCO2Na, HCO2H
View Scheme
参考文献
Johnson,W.S.; Owyang,R.
Journal of the American Chemical Society, 1964 , vol. 86, p. 5593 - 5598
反应条件
1: diethyl ether
2: diethyl ether / Behandeln des Reaktionsprodukts mit Schwefelsaeure enthaltendem Aethanol
3: H2SO4; formic acid
View Scheme
参考文献
Kappeler et al.
Helvetica Chimica Acta, 1954 , vol. 37, p. 957,962
反应条件
lithium aluminium tetrahydride; diethyl ether
参考文献
Eschenmoser; Frey
Helvetica Chimica Acta, 1952 , vol. 35, p. 1660,1665
