1: 87 percent / BF3*OEt2 / toluene / 16 h / 20 °C 2: 85 percent / NaBH4 / 5 percent Pd/C / tetrahydrofuran; H2O / 18 h / 20 °C 3: 86 percent / tetrahydrofuran / 5 h / Heating 4: 73 percent / NaH / various solvent(s); dimethylformamide / 2 h / 20 °C View Scheme
参考文献
Macleod, Calum; McKiernan, Gordon J.; Guthrie, Emma J.; Farrugia, Louis J.; Hamprecht, Dieter W.; Macritchie, Jackie; Hartley, Richard C.
Journal of Organic Chemistry, 2003 , vol. 68, # 2 p. 387 - 401
1: 68 percent / LiOMe / dimethylformamide; methanol / 16 h / 90 °C 2: 92 percent / H2 / 10percent Pd/C / 3102.9 Torr 3: 66 percent / HBF4 (48percent), isoamyl nitrite / ethanol; H2O / 0.5 h / -5 °C 4: 73 percent / KO2 / 18-crown-6 / 1,1,2-trichloro-1,2,2-trifluoro-ethane / 48 h / Ambient temperature View Scheme
参考文献
Beadle, James R.; Korzeniowsky, Stephen H.; Rosenberg, David E.; Garcia-Slanga, Blanche J.; Gokel, George W.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1594 - 1603
sodium perchlorate; peroxomonosulfate(1-) in water; acetic acid oxidation at various percentage of acetic acid, in the presence or absence of atmospheric oxiper, ΔH(excit.), ΔS(excit.) and ΔG(excit.) were given; Product distributionThermodynamic data;
参考文献
Renganathan, Rajalingam; Maruthamuthu, Pichai
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 285 - 290
