1.1: 89 percent / LDA; LiCl / tetrahydrofuran / 18 h / 0 °C 2.1: 92 percent / LiNH2*BH3 / CH2Cl2 / 3 h / -78 - 0 °C 3.1: 95 percent / imidazole; DMAP / 8 h / 25 °C 4.1: 87 percent / H2 / Pd/C / ethanol / 12 h / 25 °C 5.1: NaH / tetrahydrofuran / 1 h 5.2: 85 percent / TBAI / tetrahydrofuran / 12 h / 25 °C 6.1: 93 percent / TBAF / tetrahydrofuran / 12 h / 25 °C 7.1: 94 percent / Dess-Martin periodinane / CH2Cl2 / 1 h / 25 °C 8.1: n-BuLi / hexane; tetrahydrofuran; 1,2-dimethoxy-ethane / 0.5 h / -78 °C 8.2: hexane; tetrahydrofuran; 1,2-dimethoxy-ethane / 1 h / -78 °C 9.1: Ph2S / sunlight 10.1: 98 percent / Dess-Martin periodinane / CH2Cl2 / 0.5 h / 25 °C 11.1: 89 percent / DDQ / H2O; CH2Cl2 / 0.5 h / 25 °C / pH 7.0 12.1: 94 percent / TEMPO; bis(acetoxy)iodobenzene / CH2Cl2 / 2 h / 25 °C 13.1: BF3*OEt2 / tetrahydrofuran / 1 h / -78 °C 14.1: 86 percent / iPr2NEt / CH2Cl2 / 12 h / 25 °C 15.1: 88 percent / HF*pyridine / tetrahydrofuran / 12 h / 25 °C 16.1: 83 percent / CF3COOH / CH2Cl2 / 3 h / 0 °C 17.1: Et3N; 2,4,6-trichlorobenzoyl chloride / tetrahydrofuran / 3 h / 25 °C 17.2: 59 percent / DMAP / tetrahydrofuran; toluene / 12 h / 25 °C 18.1: hydroquinone; nBu3SnH / Mo(CO)3(tBuNC)3 / tetrahydrofuran / 12 h / 55 °C 18.2: 54 percent / I2 / CH2Cl2 / 25 °C 19.1: 90 percent / CuI / Pd(PPh3)4 / toluene / 8 h / 80 °C 20.1: 69 percent / Me2BBr / CH2Cl2 / 2 h / -78 °C 21.1: 85 percent / TEMPO; TCCA / CH2Cl2 / 1 h / 25 °C 22.1: NaClO2; NaH2PO4; 2-methyl-2-butene / 2-methyl-propan-2-ol; H2O; tetrahydrofuran / 0.5 h / 25 °C 23.1: NaBH4; CeCl3*7H2O / methanol / 1 h / 0 °C View Scheme