2-甲氧基-1-(2,4,6-三羟基苯基)乙酮合成路线 （共 27 条）
反应条件
anhydrous sodium benzoate
T=180°C; Kochen des Reaktionsprodukts mit waessrig-alkoholischer Natronlauge;
参考文献
Dwivedi, P.; Kapoor, N. K.; Khanna, R. N.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1980 , vol. 19, # 1 p. 77 - 78
反应条件
triethylamine
T=165°C; Erwaermen des Reaktionsprodukts mit wss.-aethanol. Kalilauge;
参考文献
Kuhn; Loew
Chemische Berichte, 1944 , vol. 77/79, p. 211,213
反应条件
1: potassium-salt of/the/ piperonylic acid / 180 °C / 25 Torr / Erwaermen des Reaktionsprodukts mit wss.-aethanol. Kalilauge
2: potassium carbonate; acetone
View Scheme
参考文献
Briggs; Locker
Journal of the Chemical Society, 1949 , p. 2162
反应条件
o-chloro-sodium benzoate
1) 4h, 180 deg C, reduced pressure 2) room temperature, overnight;
参考文献
Jain, A. C.; Gupta, S. K.; Bambah, P. K.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 10 p. 1002 - 1004
反应条件
1: 82 percent / potassium p-(benzyloxy)benzoate / 8 h / 160 °C
2: 63 percent / K2CO3 / acetone / Heating
3: 84 percent / AcOH, HCl / 3 h / Heating
View Scheme
参考文献
De Meyer; Haemers; Mishra; Pandey; Pieters; Vanden Berghe; Vlietinck
Journal of Medicinal Chemistry, 1991 , vol. 34, # 2 p. 736 - 746
反应条件
potassium 3-(benzyloxy)-4-methoxybenzoate
参考文献
Beutler, John A.; Hamel, Ernest; Vlietinck, Arnold J.; Haemers, Achiel; Rajan, Padinchare; Roitman, James N.; Cardellina II, John H.; Boyd, Michael R.
Journal of Medicinal Chemistry, 1998 , vol. 41, # 13 p. 2333 - 2338
反应条件
3,4-methylenedioxybenzoic acid potassium salt
T=180°C; P=25 Torr; Erwaermen des Reaktionsprodukts mit wss.-aethanol. Kalilauge;
参考文献
Briggs; Locker
Journal of the Chemical Society, 1949 , p. 2162
