Ph3P(+)CH3I(-); triphenylphosphine; Rhodium trichloride in various solvent(s) T=180°C; P=60004.8 Torr; 4 h; further ereaction conditions and promotors; Product distribution;
in cyclohexane in dry box onto the degassed (vac.) soln. of complex (in a pressure tube fitted with a Teflon stopcock) CH3CHO distilled, 5 d reacted at room temp.; not isolated, spect. detection by IR and NMR in the soln.;
参考文献
Bernard, Karen A.; Atwood, Jim D.
Organometallics, 1989 , vol. 8, p. 795 - 800
