KCl in neat (no solvent) Electrolysis; electrodeposition in fused LiCl, KCl mixture at 953 K with Cu cathode and graphite anode, constant current 1.5 A for 5 min; washed (water), at room temp., XRD;
参考文献
Materials Research Bulletin, , vol. 35, # 7 p. 1023 - 1033
succinic acid in ethanol separate dissolving of stoich. amts. of LiCH3COO*2H2O, Ni(CH3COO)2*4H2O and succinic acid in EtOH; mixing, evapn. of EtOH at 50-60°C; drying at 70°C; precalcn. at 450°C; calcn. at 650°C inair for 24 h;
KCl in neat (no solvent) Electrolysis; electrodeposition in fused LiCl, KCl mixture at 953 K with Cu cathode and graphite anode, constant current 1.5 A for 30 min; washed (water), at room temp., XRD;
参考文献
Materials Research Bulletin, , vol. 35, # 7 p. 1023 - 1033
→
反应条件
in neat (no solvent) Kinetics; heating zirconium compd. to 773-923 K under N2, flowing CO2/N2 (1:9) for30 min; powder XRD;
in further solvent(s) Electrochem. Process; Li2CO3 formed in aged films on SnO2 or WO3 electrode surfaces obtained from 1 M LiClO4 soln. in propylene carbonate; detn. by XRD, IR, XPS;
参考文献
Journal of the Electrochemical Society, , vol. 147, # 7 p. 2784 - 2795
