Peacock, Anna F.A.; Bullen, Gemma A.; Gethings, Lee A.; Williams, Jonathan P.; Kriel, Frederik H.; Coates, Judy
Journal of Inorganic Biochemistry, 2012 , vol. 117, p. 298 - 305
in tetrahydrofuran N2 atmosphere; addn. of soln of org. compd. in THF to soln. of Au-compd. in THF (0°C), stirring (15 min), warming (room temp.); concn. (vac.)pptn. on addn. of pentane, filtration, washing (pentane), drying (vac.); elem. anal.;
in acetone 48 h; Heatingformation of complexes, other uni- and polydentate phosphines;
参考文献
Salagre, Pilar; Sueiras, Jesus-Eduardo; Solans, Xavier; Germain, Gabriel
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 2263 - 2268
tetrahydrofuran in tetrahydrofuran in 10 mL of THF with 5E-3 M Mn(CO)5(1-) and 5E-3 M Mn(CO)5(PPh3)(1+) at 22°C under Ar, 0.10 mmol PEt3 added, react. complete within 5 min; further products;
tetrahydrofuran in tetrahydrofuran in 10 mL of THF with 5E-3 M NaMn(CO)5 and 5E-3 M Mn(CO)5(PPh3)PF6 at 22°C under Ar, 0.10 mmol PEt3 added, react. complete within 5 min; further products;
tetrahydrofuran in tetrahydrofuran byproducts: CO; in 10 mL of THF with 5E-3 M Mn(CO)5(1-) and 5E-3 M Mn(CO)5(PEt3)(1+) at 22°C under Ar, 0.10 mmol PEt3 added, react. complete within 5 min;
