(2Z)-2-庚烯-1-醇合成路线 （共 19 条）
反应条件
dipyridine chromium trioxide in dichloromethane
参考文献
Farmaco, Edizione Scientifica, , vol. 32, p. 627 - 634
反应条件
1: PBr3, pyridine / diethyl ether / 1) 2 h, 2) reflux, 2.5 h 2: 50 percent / Li2CuCl4 / tetrahydrofuran / 4 h / -10 °C 3: 68 percent / acetic acid / 35 - 40 °C View Scheme
参考文献
Vig, O. P.; Sharma, M. L.; Vohra, Neelam; Sabharwal, Arun; Huq, M. A.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1987 , vol. 26, # 1-12 p. 1069 - 1070
反应条件
1: CrO3*2Py / CH2Cl2 2: (i) NaH, THF, (ii) /BRN= 1700822/ 3: LiAlH4, AlCl3 / diethyl ether 4: CrO3*2Py / CH2Cl2 View Scheme
参考文献
Petragnani,N. et al.
Farmaco, Edizione Scientifica, 1977 , vol. 32, p. 627 - 634
反应条件
zinc in ethanol
2 h; Heating;
参考文献
Vig, O. P.; Sharma, M. L.; Vohra, Neelam; Sabharwal, Arun; Huq, M. A.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1987 , vol. 26, # 1-12 p. 1069 - 1070
反应条件
1.1: nBuLi / diethyl ether; hexane / 2 h / -50 °C
1.2: 78 percent / diethyl ether; hexane / 18 h / 20 °C
2.1: 62.9 percent / H2; quinoline; KOH / Lindlar catalyst / ethanol / 6 h / atmospheric pressure
View Scheme
参考文献
Mayer, Sandra F.; Steinreiber, Andreas; Orru, Romano V. A.; Faber, Kurt
European Journal of Organic Chemistry, 2001 , # 23 p. 4537 - 4542
反应条件
methanol; tert.-butyl lithium in diethyl ether
T=-15°C; 0.25 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Meyers, A. I.; Spohn, Ronald F.
Journal of Organic Chemistry, 1985 , vol. 50, # 24 p. 4872 - 4877
反应条件
in diethyl ether
1.) -50 deg C --> r.t., 1 h 2.) r.t., 1 h;
参考文献
Alexakis, A.; Cahiez, G.; Normant, J. F.
Tetrahedron, 1980 , vol. 36, # 87 p. 1961 - 1970
反应条件
perchloric acid in diethyl ether
T=0°C; 0.5 h; Yield given. Yields of byproduct given;
参考文献
Shimizu, Nobujiro; Imazu, Sachiko; Shibata, Fumihiro; Tsuno, Yuho
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 4 p. 1122 - 1128
反应条件
1: aq. HCl / dimethylsulfoxide
2: H2 / Lindlar catalyst / hexane
View Scheme
参考文献
Petragnani,N. et al.
Farmaco, Edizione Scientifica, 1977 , vol. 32, p. 627 - 634
反应条件
copper(II) sulfate in water; dimethyl sulfoxide
T=105 - 117°C; 0.25 h; Title compound not separated from byproducts;
参考文献
Korneva, O. S.; Nefedov, O. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 11.1 p. 2194 - 2196
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 11 p. 2518 - 2520
