(2Z)-2-庚烯-1-醇合成路线 （共 19 条）
反应条件
copper(II) sulfate in water; dimethyl sulfoxide
T=105 - 117°C; 0.25 h; Title compound not separated from byproducts;
参考文献
Korneva, O. S.; Nefedov, O. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 11.1 p. 2194 - 2196
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 11 p. 2518 - 2520
反应条件
1: diisobutylaluminum hydride / diethyl ether / 0.25 h / 0 °C
2: 1.) t-BuLi, 2.) methanol / diethyl ether / 0.25 h / -15 °C
View Scheme
参考文献
Meyers, A. I.; Spohn, Ronald F.
Journal of Organic Chemistry, 1985 , vol. 50, # 24 p. 4872 - 4877
反应条件
1: silica gel-aq. oxalic acid / CH2Cl2 / 0.5 h / 0 °C
2: diisobutylaluminum hydride / diethyl ether / 0.25 h / 0 °C
3: 1.) t-BuLi, 2.) methanol / diethyl ether / 0.25 h / -15 °C
View Scheme
参考文献
Meyers, A. I.; Spohn, Ronald F.
Journal of Organic Chemistry, 1985 , vol. 50, # 24 p. 4872 - 4877
反应条件
dihydrogen peroxide; trimethylamine in tetrahydrofuran; water
2 h; Ambient temperature; Title compound not separated from byproducts;
参考文献
Zaidlewicz, Marek
Journal of Organometallic Chemistry, 1985 , vol. 293, p. 139 - 146
反应条件
chloro-(2-methylpropyl)magnesium; bis(cyclopentadienyl)titanium dichloride
2) THF, 0 deg C, then r.t.; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Sato, Fumie; Ishikawa, Hiroaki; Watanabe, Hiroshi; Miyake, Tooru; Sato, Masao
Journal of the Chemical Society, Chemical Communications, 1981 , # 14 p. 718 - 720
参考文献
Colonge; Poilane
Bulletin de la Societe Chimique de France, 1955 , p. 953
参考文献
Smets
Mem.Acad.Belg.8gradChem.Abstr., 1947 , vol. 21, # 1 p. 56
Mem.Acad.Belg.8gradChem.Abstr., 1950 , p. 8315
反应条件
Cl2Ni(1,2-bis(diphenylphosphino)ethane)
4 h; Ambient temperature; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Menicagli, Rita; Malanga, Corrado; Finato, Barbara; Lardicci, Luciano
Gazzetta Chimica Italiana, 1989 , vol. 119, # 1 p. 69 - 70
反应条件
pyridine; phosphorus tribromide in diethyl ether
1) 2 h, 2) reflux, 2.5 h;
参考文献
Vig, O. P.; Sharma, M. L.; Vohra, Neelam; Sabharwal, Arun; Huq, M. A.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1987 , vol. 26, # 1-12 p. 1069 - 1070
