反应条件
1: 98 percent / toluene / Heating
2: 95 percent / DIBAL-H / diethyl ether; hexane / 1 h / 0 °C
3: 94 percent / (COCl)2; DMSO; Et3N / CH2Cl2 / -78 - 20 °C
4: 99 percent / toluene / Heating
5: DIBAL-H / diethyl ether; hexane / 1 h / 0 °C
6: 9.9 g / (COCl)2; DMSO; Et3N / CH2Cl2 / -78 - 20 °C
7: 92 percent / toluene / Heating
8: 97 percent / DIBAL-H / diethyl ether; hexane / 1 h / 20 °C
9: 57 percent / (COCl)2; DMSO; Et3N / CH2Cl2 / -78 - 20 °C
View Scheme
参考文献
Busch, Benjamin; Ueberschaar, Nico; Behnken, Swantje; Sugimoto, Yuki; Werneburg, Martina; Traitcheva, Nelly; He, Jing; Hertweck, Christian
Angewandte Chemie - International Edition, 2013 , vol. 52, # 20 p. 5285 - 5289
Angew. Chem., 2013 , vol. 125, # 20 p. 5393 - 5397,5
