water in water; toluene; butan-1-ol (CH3)2SiCl2 and SiCl4 (5:1 mol) in butanol-H2O-toluene; heating of the oily product at 350-600°C in a slow stream of N2;; fractional distn.; crystn. on cooling; recrystn. from toluene;;
参考文献
Journal of the American Chemical Society, , vol. 68, p. 356 - 358
NaOH in water byproducts: C2H5OH; heating of (CH3)2Si(OC2H5)2, (CH3)3Si(OC2H5) and an excess (50percent) of H2O in presence of NaOH; sepn. of C2H5OH by distn.; boiling of the residue with 20percent aq. HCl; further products;; distn.;;
参考文献
Journal of the American Chemical Society, , vol. 68, p. 2284 - 2290
water in toluene T=20°C; 27 h; influence of salts and HCl-concentration; or copolymerization with Me3SiCl; other methylchlorosilane; Product distribution;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 61, # 3.2 p. 762 - 769,692 - 697
