bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-di(diphenylphosphino)-butane in dimethyl sulfoxide T=30 - 80°C; 9 h; DarknessAerobic condition;

triethylamine; palladium complex immobilised on silica gel in various solvent(s) T=70°C; Sonogashira coupling; 12 h;

bis-triphenylphosphine-palladium(II) chloride in N,N,N',N',N'',N''-hexamethylphosphoric triamide T=80°C; 1 h;

1: 4-(2'-bromoethynyl)-1-fluorobenzene With n-butyllithium in tetrahydrofuran; hexane T=-78 - -30°C; deprotonation; 2: 1-bromo-2-(p-methylphenyl)acetylene With zinc dibromide; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; hexane T=0 - 25°C; Substitution;

4-(N,N-dimethlyamino)pyridine; copper(l) iodide in acetonitrile T=20°C; 72 h; Darkness;

piperidine; C34H22Cl4CoCu2N10O4(1-)*C8H20N(1+); oxygen in neat (no solvent) T=25°C; 4 h;

N,N,N',N,-tetramethylethylenediamine; phosphoric acid in N,N-dimethyl-formamide T=20°C; 1 h; TimeSolventReagent/catalyst;

piperidine; C34H22Cl4Cu2FeN10O4(1-)*C8H20N(1+); oxygen in neat (no solvent) T=25°C; 4 h; Catalytic behavior; Reagent/catalyst;