反应条件
1.1: 70 percent / Pd2(dba)3*CHCl3; (S,S)-1,2-bis(2-Ph2P-C6H4-CONH)cyclohexane
2.1: 72 percent / K2OsO4*H2O; (DHQD)2PYR
3.1: TEMPO; NaOCl
4.1: NaClO2
5.1: 95 percent / BOP
6.1: LiN3
7.1: PMe3
8.1: BOP
9.2: NaBH4
10.1: (COOOH)2
11.1: LiOH / 0 °C
12.1: TFA / CH2Cl2 / 0 °C
13.1: 56 percent / PyAOP; Hunig's base
14.1: H2 / Pd/C
15.1: LiOH / 20 °C
View Scheme
参考文献
Tanaka, Hiroko; Sawayama, Andrew M.; Wandless, Thomas J.
Journal of the American Chemical Society, 2003 , vol. 125, # 23 p. 6864 - 6865
