三-O-苄基-D-葡萄烯糖合成路线 （共 122 条）
反应条件
1: NaH 2: 43 percent / BF3*OEt2 / CH2Cl2 / 2 h / -15 °C 3: 85 percent / MCPBA, NaHCO3 / CH2Cl2 / 1.5 h / 20 °C 4: 6 percent / SmI2, cyclohexanone / tetrahydrofuran / 0.17 h / 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 4, # 4 p. 655 - 671
反应条件
1: 43 percent / BF3*OEt2 / CH2Cl2 / 2 h / -15 °C 2: 85 percent / MCPBA, NaHCO3 / CH2Cl2 / 1.5 h / 20 °C 3: 6 percent / SmI2, cyclohexanone / tetrahydrofuran / 0.17 h / 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 4, # 4 p. 655 - 671
反应条件
1: NaH / dimethylformamide / 1.) 0 deg C, 20 min, 2.) 20 deg C, 1 h 2: MCPBA, NaHCO3 / CH2Cl2 / 1.5 h / 20 °C 3: 9 percent / SmI2, cyclohexanone / tetrahydrofuran / 0.17 h / 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 4, # 4 p. 655 - 671
反应条件
1: 85 percent / MCPBA, NaHCO3 / CH2Cl2 / 1.5 h / 20 °C 2: 6 percent / SmI2, cyclohexanone / tetrahydrofuran / 0.17 h / 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 4, # 4 p. 655 - 671
反应条件
1: MCPBA, NaHCO3 / CH2Cl2 / 3 h / 20 °C 2: SmI2 / tetrahydrofuran / 24 h / 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 3, # 8 p. 1342 - 1356
反应条件
1: 69 percent / MCPBA, NaHCO3 / CH2Cl2 / 3 h / 20 °C 2: 72 percent / SmI2 / tetrahydrofuran / 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 3, # 8 p. 1342 - 1356
反应条件
1: 87 percent / MCPBA, NaHCO3 / CH2Cl2 / 3 h / 20 °C 2: 22 percent / SmI2 / tetrahydrofuran / 24 h / 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 3, # 8 p. 1342 - 1356
反应条件
1: p-methylphenyl 3,4,6-tri-O-benzyl-2-deoxy-1-thio-α-D-glucopyranoside; N,N-dimethyl-formamide in chloroform-d1 T=20°C; 2: trimethylsilyl trifluoromethanesulfonate With N-iodo-succinimide in chloroform-d1 T=20°C;
参考文献
European Journal of Organic Chemistry, , vol. 2014, # 9 p. 1827 - 1831
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; samarium diiodide in tetrahydrofuran 15 h; Ambient temperature;
参考文献
Bulletin de la Societe Chimique de France, , vol. 130, # 3 p. 256 - 265
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; samarium diiodide in tetrahydrofuran Ambient temperature;
参考文献
Bulletin de la Societe Chimique de France, , vol. 130, # 3 p. 256 - 265
