in neat (no solvent)
byproducts: CF3I; carried out in an inert atm., reactor loaded with educts and heated to 165°C; only trace amounts (0.2percent) detected by NMR;
参考文献
Ganja, E. A.; Morrison, J. A.
Inorganic Chemistry, 1990 , vol. 29, p. 33 - 38
in neat (no solvent)
byproducts: CF3I; carried out under inert atm.; freshly sublimed GeI4 and Te-compd. allowed to interact at 170°C for 120h, or for 150h at 120, 140 and 150°C; not isolated, monitored by NMR;
参考文献
Ganja, E. A.; Morrison, J. A.
Inorganic Chemistry, 1990 , vol. 29, p. 33 - 38
diethylene glycol dimethyl ether in monofluoro-trichloromethane
T=0°C; 24 h; var. ratio of perfluoroorgano-tellur/dialkylmetal compound, solvent, temp., time; MechanismProduct distribution;
参考文献
Herberg, S.; Lange, H.; Naumann, D.
Journal of Fluorine Chemistry, 1987 , vol. 35, p. 267 - 274