1,1-二氯-4-甲基-1,3-戊二烯合成路线 （共 44 条）
反应条件
copper Erhitzen des Reaktionsprodukts mit Essigsaeure und wss. HCl;
参考文献
Farkas et al.
Collection of Czechoslovak Chemical Communications, 1959 , vol. 24, p. 2230,2235
反应条件
in 1,4-dioxane T=135 - 140°C; Sealed tubeInert atmosphere;
参考文献
Russian Chemical Bulletin, , vol. 61, # 6 p. 1138 - 1147
Izv. Akad. Nauk, Ser. Khim., , vol. 61, # 6 p. 1129 - 1138,10
反应条件
1: 20 percent / Cu2O, CuCl, dibutylamine / 1 h / 100 - 110 °C 2: 87 percent / Zn/Cu / methanol 3: 80 percent / HCl / 4 h / Ambient temperature 4: NaOMe / methanol / 2 h / 50 °C 5: 95 percent / NaOH / methanol / 8 h / 40 °C 6: 3.52 g / Et3N / acetone / 3 h / 35 °C View Scheme
参考文献
Badanyan; Stepanyan; Mikaelyan; Ovivyan; Panosyan
Russian Journal of Organic Chemistry, 1997 , vol. 33, # 1 p. 34 - 41
反应条件
1: 20 percent / Cu2O, CuCl, dibutylamine / 1 h / 100 - 110 °C 2: 87 percent / Zn/Cu / methanol 3: 80 percent / HCl / 4 h / Ambient temperature 4: NaOMe / methanol / 2 h / 50 °C 5: 95 percent / NaOH / methanol / 8 h / 40 °C 6: 3.52 g / Et3N / acetone / 3 h / 35 °C View Scheme
参考文献
Badanyan; Stepanyan; Mikaelyan; Ovivyan; Panosyan
Russian Journal of Organic Chemistry, 1997 , vol. 33, # 1 p. 34 - 41
反应条件
dibutylamine; 2,2,2-trichloroacetyl chloride; copper(I) bromide
T=100 - 110°C; 10 h;
参考文献
Badanyan; Stepanyan; Mikaelyan; Ovivyan; Panosyan
Russian Journal of Organic Chemistry, 1997 , vol. 33, # 1 p. 34 - 41
反应条件
dibutylamine; copper(I) bromide
T=100 - 110°C; 10 h;
参考文献
Badanyan; Stepanyan; Mikaelyan; Ovivyan; Panosyan
Russian Journal of Organic Chemistry, 1997 , vol. 33, # 1 p. 34 - 41
反应条件
Rh2(pfb)4
T=22°C; 2 h; variation of catalyst; Product distribution;
参考文献
Anciaux, A. J.; Demonceau. A; Noels, A. F.; Warin, R.; Hubert, A. J.; Teyssie, P.
Tetrahedron, 1983 , vol. 39, # 13 p. 2169 - 2173
反应条件
Rh2(pfb)4
T=22°C; 4 h; Title compound not separated from byproducts;
参考文献
Anciaux, A. J.; Demonceau. A; Noels, A. F.; Warin, R.; Hubert, A. J.; Teyssie, P.
Tetrahedron, 1983 , vol. 39, # 13 p. 2169 - 2173
反应条件
potassium acetate; acetic anhydride; acetic acid in water
参考文献
Imperial Chemical Industries Limited
Patent: US4310464 A1, 1982 ;
反应条件
acetic anhydride; acetic acid
参考文献
Imperial Chemical Industries Limited
Patent: US4310464 A1, 1982 ;
