[RuIII(2,4-pentanedionato)3]; methanesulfonic acid; hydrogen; 1,1,1-tris (diphenylphosphinomethyl)ethane in tetrahydrofuran T=200°C; P=7500.75 Torr; 16 h; AutoclaveInert atmosphere;

1: [RuIII(2,4-pentanedionato)3]; 1,1,1-tris (diphenylphosphinomethyl)ethane; methanesulfonic acid; hydrogen / tetrahydrofuran / 16 h / 200 °C / 7500.75 Torr / |Autoclave; |Inert atmosphere 2: triethylamine / dichloromethane / 0 - 20 °C 3: [RuIII(2,4-pentanedionato)3]; 1,1,1-tris (diphenylphosphinomethyl)ethane; methanesulfonic acid; hydrogen / tetrahydrofuran / 16 h / 200 °C / 7500.75 Torr / |Autoclave; |Inert atmosphere View Scheme

1: [RuIII(2,4-pentanedionato)3]; 1,1,1-tris (diphenylphosphinomethyl)ethane; methanesulfonic acid; hydrogen / tetrahydrofuran / 16 h / 200 °C / 7500.75 Torr / |Autoclave; |Inert atmosphere 2: triethylamine / dichloromethane / 0 - 20 °C 3: [RuIII(2,4-pentanedionato)3]; 1,1,1-tris (diphenylphosphinomethyl)ethane; methanesulfonic acid; hydrogen / tetrahydrofuran / 16 h / 200 °C / 7500.75 Torr / |Autoclave; |Inert atmosphere View Scheme

1: [RuIII(2,4-pentanedionato)3]; 1,1,1-tris (diphenylphosphinomethyl)ethane; methanesulfonic acid; hydrogen / tetrahydrofuran / 16 h / 200 °C / 7500.75 Torr / |Autoclave; |Inert atmosphere 2: [RuIII(2,4-pentanedionato)3]; 1,1,1-tris (diphenylphosphinomethyl)ethane; methanesulfonic acid; hydrogen / tetrahydrofuran / 16 h / 220 °C / 7500.75 Torr / |Autoclave; |Inert atmosphere View Scheme

water; hydrogen; 1,1,1-tris(diphenylphosphinomethyl)-ethane in tetrahydrofuran T=164°C; P=30003 Torr; 14 h;

water; hydrogen; 1,1,1-tris(diphenylphosphinomethyl)-ethane in tetrahydrofuran T=100°C; P=30003 Torr; 14 h;

hydrogen; palladium (II) 2,4-pentanedionate in toluene T=100°C; P=45004.5 Torr; 20 h; Autoclave; regioselective reaction;

palladium (II) 2,4-pentanedionate in toluene T=100°C; P=30003 Torr; 20 h; AutoclaveInert atmosphere; Catalytic behavior; SolventReagent/catalyst; regioselective reaction;

palladium (II) 2,4-pentanedionate in toluene T=100°C; P=30003 Torr; 20 h; AutoclaveInert atmosphere; regioselective reaction;

1: 2.) H2 / 2.) PtO2 / 1.) ether, THF, 20 deg C, 4 h 2: 6 N aq. NaOH / methanol / 0.42 h / Heating View Scheme