in gaseous matrix Electric Arc; feeding He/ZnEt2 mixt. into flash electric discharge flow-type cell with quartz windows (tungsten electrodes, p(He)=133-1330 Pa, p(ZnEt2)=1.33-133 Pa, condensors battery (0.1 μF) charged to 20 kV, pulse (several A for 0.2 μs); emission UV spectroscopy;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 52, p. 1006 - 1013
Zhurnal Obshchei Khimii, , vol. 52, p. 1149 - 1156
chiral R-(-)-β-amino alcohol in toluene T=-20°C; 30 h; kinetic resolution of some rac. aldehydes; var. of chiral catalyst; Product distributionMechanism;
参考文献
Hayashi, Masahiko; Miwata, Hiroshi; Oguni, Nobuki
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 5 p. 1167 - 1171