3,3-二甲基-1-丁烯合成路线 （共 347 条）
反应条件
1: zinc/copper couple; trichlorophosphate / diethyl ether / Reflux 2: acetic acid; zinc / 7 h / 20 - 80 °C 3: dihydrogen peroxide; AcrH(+)ClO4(-) / water; acetonitrile / 20 h / 20 °C / UV-irradiation View Scheme
参考文献
Xu, Hua-Jian; Zhu, Feng-Fei; Shen, Yong-Ya; Wan, Xin; Feng, Yi-Si
Tetrahedron, 2012 , vol. 68, # 22 p. 4145 - 4151
反应条件
in diethyl ether adding N-N'-ligand (30percent molar excess) and olefin to soln./suspn. of dimethyl sulfide complex in diethyl ether, stirring (15 h, room temp.), pptn.; filtering, drying, recrystn. (methylene chloride - diethyl ether); mixt. with 45percent of rotamer;
参考文献
Cucciolito, Maria Elena; Felice, Vincenzo De; Panunzi, Achille; Vitagliano, Aldo
Organometallics, 1989 , vol. 8, p. 1180 - 1187
反应条件
1: aqueous hydrogen peroxide; formic acid / und Erwaermen des Reaktionsprodukts mit wss.Natronlauge 2: sodium periodate; aqueous sulfuric acid View Scheme
参考文献
Braendstroem
Acta Chemica Scandinavica (1947-1973), 1959 , vol. 13, p. 608
反应条件
IrH2{C6H3-2,6-(CH2PBu(t)2)2} in 1,3,5-trimethyl-benzene T=55°C; Kinetics;
参考文献
Renkema, Kenton B.; Kissin, Yury V.; Goldman, Alan S.
Journal of the American Chemical Society, 2003 , vol. 125, # 26 p. 7770 - 7771
反应条件
P=5 - 150 Torr; Ambient temperatureIrradiationpresence/absence of oxygen, DI; Quantum yield;
参考文献
Deslauriers, Helene; Collin, Guy J.
Canadian Journal of Chemistry, 1985 , vol. 63, p. 62 - 67
反应条件
oxygen; benzil in benzene T=5°C; 2 h; Irradiation;
参考文献
Bartlett, Paul D.; Roof, Antonius A.M.; Shimizu, Nobujiro
Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3130 - 3131
反应条件
di-tert-butyl peroxide T=140 - 150°C; 3.5 h;
参考文献
Abramovici,M.; Pines,H.
Journal of Organic Chemistry, 1969 , vol. 34, p. 266 - 270
反应条件
(iPr3P)2IrH5 T=150°C; 120 h; reaction time; other catalysts: <(p-F-C6H4)3P>2IrH5, <(p-F-C6H4)3P>3RuH4, (Me3P)2IrH5, (Ph3P)3RuH4, (Ar3P)2ReH7; Product distributionMechanism;
参考文献
Felkin, Hugh; Fillebeen-Khan, Tauqir; Gault, Yvonne; Holmes-Smith, Rupert; Zakrzewski, Janusz
Tetrahedron Letters, 1984 , vol. 25, # 12 p. 1279 - 1282
反应条件
aluminum oxide; {4-Me2N-C6H2-2,6-[OP(t-Bu)2]2}IrH2 T=125°C; 0.166667 - 4 h; Product distribution / selectivity;
参考文献
WO2008/153869 A2, ;
Page/Page column 20-21 ;
反应条件
C18H32ClIrOP2S; sodium t-butanolate T=100°C; 4 h; Inert atmosphereSchlenk techniqueGloveboxSealed tube;
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 5 p. 1390 - 1394
Angew. Chem., , vol. 126, # 5 p. 1414 - 1418
