3,3-二甲基-1-丁烯合成路线 （共 347 条）
反应条件
neopentane2,2-dimethylpropane; dichloromethane; [14C]-1,1-Dichloroethylene T=14 - 15°C; 1 h; Irradiationfree-radical isomerization of N-bromosuccinimide to β-bromopropionyl isocyanate, photolysis in the presence of halogen scavengers, halogens; dependence on NBS concentration, effect of alkenes; isomerization of other succinimides and glutarimides; Product distributionRate constant;
参考文献
Journal of the American Chemical Society, , vol. 104, # 25 p. 7257 - 7267
反应条件
P=5 - 150 Torr; Ambient temperatureIrradiationpresence/absence of oxygen, DI; Quantum yield;
参考文献
Deslauriers, Helene; Collin, Guy J.
Canadian Journal of Chemistry, 1985 , vol. 63, p. 62 - 67
反应条件
rhenium bis triphenylphosphine heptahydride; phosphorous acid trimethyl ester 1.) 70 deg C, 40 min; 2.) 60 deg C, 1 h; other objects: selectivity; n-alkanes: n-heptane, n-octane; Product distributionMechanism;
参考文献
Baudry, Denise; Ephritikhine, Michel; Felkin, Hugh; Zakrzewski, Janusz
Tetrahedron Letters, 1984 , vol. 25, # 12 p. 1283 - 1286
反应条件
tri-ruthenium(0)dodecacarbonyl in acetonitrile T=135°C; 6 h;
参考文献
Ko, Sangwon; Han, Hoon; Chang, Sukbok
Organic Letters, 2003 , vol. 5, # 15 p. 2687 - 2690
反应条件
(i) (CF3CO2)2Hg, (ii) aq. NaOH, NaBH4; Multistep reaction;
参考文献
Brown, Herbert C.; Kurek, Joseph T.; Rei, Min-Hon; Thompson, Kerry L.
Journal of Organic Chemistry, 1985 , vol. 50, # 8 p. 1171 - 1174
反应条件
sodium hydroxide; sodium tetrahydroborate; mercury(II) trifluoroacetate 1.) 1440 min; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Brown, Herbert C.; Kurek, Joseph T.; Rei, Min-Hon; Thompson, Kerry L.
Journal of Organic Chemistry, 1984 , vol. 49, # 14 p. 2551 - 2557
反应条件
(i) Hg(F3CCO2)2, (ii) aq. NaOH, NaBH4; Multistep reaction;
参考文献
Brown, Herbert C.; Kurek, Joseph T.; Rei, Min-Hon; Thompson, Kerry L.
Journal of Organic Chemistry, 1985 , vol. 50, # 8 p. 1171 - 1174
反应条件
sodium hydroxide; sodium tetrahydroborate; Hg(NO3)2 1.) 5 min; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Brown, Herbert C.; Kurek, Joseph T.; Rei, Min-Hon; Thompson, Kerry L.
Journal of Organic Chemistry, 1984 , vol. 49, # 14 p. 2551 - 2557
反应条件
Mo(=CHCMe2Ph)(N=C6H4iPr2)[OC(Me)(CF3)2]2; 2,6-di(O-PtBu4)C6H3Ir(C2H4) T=125°C; 24 h; Further byproducts.;
参考文献
Ahuja, Ritu; Kundu, Sabuj; Goldman, Alan S.; Brookhart, Maurice; Vicente, Brian C.; Scott, Susannah L.
Chemical Communications, 2008 , # 2 p. 253 - 255
反应条件
in tetrachloromethane 1) -20 deg C, 2) up to rt;
参考文献
Tetrahedron, , vol. 37, # 18 p. 3115 - 3120
