3,3-二甲基-1-丁烯合成路线 （共 347 条）
反应条件
N-bromosuccinmide in diethyl ether; water
参考文献
Dewey,C.S.; Bafford,R.A.
Journal of Organic Chemistry, 1965 , vol. 30, p. 491 - 495
反应条件
thionyl chloride in dichloromethane
参考文献
Still, Ian W. J.; Wilson, Donna Kaye T.
Canadian Journal of Chemistry, 1992 , vol. 70, # 3 p. 964 - 973
反应条件
lt;RhH(PEt3)3gt;; hydrogen in ethanol
T=120°C; P=30400 Torr; 16 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
MacDougall, Joanna K.; Simpson, Michael C.; Green, Michael J.; Cole-Hamilton, David J.
Journal of the Chemical Society - Dalton Transactions, 1996 , # 6 p. 1161 - 1172
反应条件
T=-78°C; 168 h; Yields of byproduct given;
参考文献
Service, Colin F.; Tipping, Anthony E.
Journal of Fluorine Chemistry, 1982 , vol. 19, p. 91 - 96
反应条件
1: NaHCO3 / propan-2-ol / 24 h / 40 °C
2: NaBH4 / methanol / 1 h / Heating
View Scheme
参考文献
Kai, Hiroyuki; Matsumoto, Hiroshi; Hattori, Naohiko; Takase, Akira; Fujiwara, Tamio; Sugimoto, Hirohiko
Bioorganic and Medicinal Chemistry Letters, 2001 , vol. 11, # 15 p. 1997 - 2000
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; 1,3-bis-(diphenylphosphino)propane; hydrogen in water; toluene
T=120°C; P=7500.75 Torr; 20 h; Overall yield = 85 percentChromat.; regioselective reaction;
参考文献
Uhlemann, Marcus; Doerfelt, Stephan; Boerner, Armin
Tetrahedron Letters, 2013 , vol. 54, # 18 p. 2209 - 2211
反应条件
hydrogen; rhodium in benzene
T=80°C; P=58840.6 Torr; 3 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Gueven, Sabriye; Nieuwenhuizen, Marko M. L.; Hamers, Bart; Franke, Robert; Priske, Markus; Becker, Marc; Vogt, Dieter
ChemCatChem, 2014 , vol. 6, # 2 p. 603 - 610
反应条件
carbon dioxide; sodium methylate in methanol
(electrolysis);
参考文献
Brettle,R.; Sutton,J.R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1975 , p. 1947 - 1954
反应条件
C18H32ClIrOP2S; sodium t-butanolate in para-xylene
T=120°C; 12 h; Inert atmosphereSchlenk techniqueGloveboxSealed tube;
参考文献
Yao, Wubing; Zhang, Yuxuan; Jia, Xiangqing; Huang, Zheng
Angewandte Chemie - International Edition, 2014 , vol. 53, # 5 p. 1390 - 1394
Angew. Chem., 2014 , vol. 126, # 5 p. 1414 - 1418
反应条件
lithium perchlorate in nitromethane
T=20°C;
参考文献
Borisov, A. V.; Bodrikov, I. V.; Borisova, G. N.; Smit, V. A.; Lutsenko, A. I.; Bel'skii, V. K.
Russian Journal of Organic Chemistry, 1995 , vol. 31, # 7 p. 943 - 951
Zhurnal Organicheskoi Khimii, 1995 , vol. 31, # 7 p. 1018 - 1026
