1-溴-1,1,2,2,3,3,4,4-七氟丁烷合成路线 (共 8 条)
反应条件
methanol; carbon dioxide; tetra-n-butylammonium tetrafluoroborate
T=50°C; P=71255.7 Torr; electrolysis: copper foil as cathode, platinum grid as anode, Ag quasi-reference electrode, -3.0 V, 2000 C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mazin; Mysov; Sterlin; Grinberg
Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35
反应条件
methanol; carbon dioxide; tetra-n-butylammonium tetrafluoroborate
T=50°C; P=71255.7 Torr; electrolysis: stainless steel grid as cathode, platinum grid as anode, Ag quasi-reference electrode, -3.0 V, 2700 C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mazin; Mysov; Sterlin; Grinberg
Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35
反应条件
tetra-n-butylammonium tetrafluoroborate
T=50°C; P=71255.7 Torr; electrolysis: copper foil as cathode, platinum grid as anode, Ag quasi-reference electrode, -3.0 V, 2000 C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mazin; Mysov; Sterlin; Grinberg
Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35
反应条件
tetra-n-butylammonium tetrafluoroborate
T=50°C; P=71255.7 Torr; electrolysis: copper foil as cathode, platinum grid as anode, Ag quasi-reference electrode, -3.0 V, 2000 C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mazin; Mysov; Sterlin; Grinberg
Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35
反应条件
tetra-n-butylammonium tetrafluoroborate
T=50°C; P=71255.7 Torr; electrolysis: stainless steel grid as cathode, platinum grid as anode, Ag quasi-reference electrode, -3.0 V, 2700 C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mazin; Mysov; Sterlin; Grinberg
Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35
反应条件
hydrogen bromide
Irradiation.mit UV-Licht;
参考文献
Haszeldine; Steele
Journal of the Chemical Society, 1954 , p. 3747,3751
参考文献
Harris,J.F.
Journal of Organic Chemistry, 1965 , vol. 30, p. 2182 - 2190
反应条件
im UV-Licht.Irradiation;
参考文献
Haszeldine; Steele
Journal of the Chemical Society, 1954 , p. 3747,3751