4',5'-亚甲基二氧-2'-硝基苯乙酮合成路线 (共 6 条)
反应条件
nitric acid in nitromethane T=20°C; 2.5 h;
参考文献
Gao, Xiaolian
Patent: US6965040 B1, 2005 ;
Location in patent: Page/Page column 24 ;
反应条件
nitric acid in water; acetic acid T=3 - 20°C; Nitration; deacetylation; 3.75 h; Title compound not separated from byproducts;
参考文献
McGall, Glenn H.; Barone, Anthony D.; Diggelmann, Martin; Fodor, Stephen P. A.; Gentalen, Erik; Ngo, Nam
Journal of the American Chemical Society, 1997 , vol. 119, # 22 p. 5081 - 5090
反应条件
in dichloromethane T=25°C;
参考文献
Teague, Simon J.
Tetrahedron Letters, 1996 , vol. 37, # 32 p. 5751 - 5754
反应条件
hydrogen; palladium on activated charcoal in ethanol
参考文献
Bertha, P.; Fetter, J.; Lempert, K.; Moeller, J.; Radics, L.
Journal of Chemical Research, Miniprint, 1980 , # 12 p. 4737 - 4744
反应条件
1: 78 percent / dimethylformamide / 1 h / 100 °C 2: 91 percent / cyclohexane / Pd/C / ethanol / 0.25 h / Heating View Scheme
参考文献
Tois, Jan; Vahermo, Mikko; Koskinen, Ari
Tetrahedron Letters, 2005 , vol. 46, # 5 p. 735 - 737
反应条件
chloroform; alkaline aqueous sodium hypochlorite solution
参考文献
Mosettig; Czadek
Monatshefte fuer Chemie, 1931 , vol. 57, p. 291,301