2,4,5-三氯三氟甲苯合成路线 （共 12 条）
反应条件
sulfuric acid; d-N,a-dimethylphenethylamine 1) 100 deg C, 24 h; Yield given. Multistep reaction;
参考文献
Castaner, J.; Riera, J.; Carilla, J.; Robert, A.; Molins, E.; Miravitlles, C.
Journal of Organic Chemistry, 1991 , vol. 56, # 1 p. 103 - 110
反应条件
1-methyl-pyrrolidin-2-one; ammonia T=0 - 190°C; 8 h;
参考文献
FINCHIMICA S.p.A.
Patent: EP1528052 A1, 2005 ;
Location in patent: Page/Page column 7 ;
反应条件
sulfuric acid; chlorine; AlCl3, aluminium chloride; iron
T=110°C; Product distribution / selectivity;
参考文献
Zhejiang Weihua Chemical Co., Ltd.
Patent: US2009/240083 A1, 2009 ;
Location in patent: Page/Page column 3 ;
反应条件
hydrogen fluoride
T=5 - 120°C; P=15001.5 Torr; 2 h; Product distribution / selectivity;
参考文献
FINCHIMICA S.p.A.
Patent: EP1528052 A1, 2005 ;
Location in patent: Page/Page column 6 ;
反应条件
aluminium trichloride
1a) 8 h, r.t., 1b) 16 h, -10 deg C;
参考文献
Castaner, J.; Riera, J.; Carilla, J.; Robert, A.; Molins, E.; Miravitlles, C.
Journal of Organic Chemistry, 1991 , vol. 56, # 1 p. 103 - 110
反应条件
aluminium trichloride
1a) 8 h, r.t., 1b) 16 h, -10 deg C;
参考文献
Castaner, J.; Riera, J.; Carilla, J.; Robert, A.; Molins, E.; Miravitlles, C.
Journal of Organic Chemistry, 1991 , vol. 56, # 1 p. 103 - 110
反应条件
chlorine; iron(III) chloride
T=80°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Ushakov, A. A.; Alikhanov, P. P.; Motsarev, G. V.; Kalinachenko, V. R.; Kuznetsova, G. N.; Kolbasov, V. I.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, p. 1993 - 1996
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 10 p. 2187 - 2191
反应条件
chlorine; iron(III) chloride
T=80°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Ushakov, A. A.; Alikhanov, P. P.; Motsarev, G. V.; Kalinachenko, V. R.; Kuznetsova, G. N.; Kolbasov, V. I.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, p. 1993 - 1996
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 10 p. 2187 - 2191
反应条件
chlorine; iron(III) chloride
T=80°C; Product distribution;
参考文献
Alikhanov, P. P.; Ushakov, A. A.; Kuznetsova, G. N.; Kalinachenko, V. R.; Motsarev, G. V.
Journal of Organic Chemistry USSR (English Translation), 1985 , vol. 21, p. 734 - 740
Zhurnal Organicheskoi Khimii, 1985 , vol. 21, # 4 p. 809 - 817
反应条件
chlorine; iron(III) chloride
T=80°C; other time; Product distribution;
参考文献
Ushakov, A. A.; Alikhanov, P. P.; Motsarev, G. V.; Kalinachenko, V. R.; Kuznetsova, G. N.; Kolbasov, V. I.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, p. 1993 - 1996
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 10 p. 2187 - 2191
