2,2-二甲基-1,3-环己烷二酮合成路线 （共 36 条）
反应条件
boron trifluoride diethyl etherate in dichloromethane
-78 deg C, then allowed to warm up to room temperature;
参考文献
Wu, Yong-Jin; Burnell, D. Jean
Tetrahedron Letters, 1989 , vol. 30, # 9 p. 1021 - 1024
反应条件
AlCl3, aluminium chloride in dichloromethane
T=20°C; Diels-Alder Cycloaddition; 0.5 h;
参考文献
Eddy, Nicholas A.; Richardson, Jay J.; Fenteany, Gabriel
European Journal of Organic Chemistry, 2013 , # 23 p. 5041 - 5044
反应条件
1: 96 percent / TsOH / benzene / Heating
2: 88 percent / KH / tetrahydrofuran / -78 °C
3: 68 percent / O3 / CH2Cl2 / -78 °C
View Scheme
参考文献
Demir, Ayhan S.; Enders, Dieter
Advanced Synthesis and Catalysis, 1997 , vol. 339, # 6 p. 553 - 563
反应条件
1: 66 percent / nBuLi / hexamethylphosphoric acid triamide; tetrahydrofuran / -100 °C
2: 88 percent / KH / tetrahydrofuran / -78 °C
3: 68 percent / O3 / CH2Cl2 / -78 °C
View Scheme
参考文献
Demir, Ayhan S.; Enders, Dieter
Advanced Synthesis and Catalysis, 1997 , vol. 339, # 6 p. 553 - 563
反应条件
1: 98 percent / TsOH / benzene / Heating
2: 66 percent / nBuLi / hexamethylphosphoric acid triamide; tetrahydrofuran / -100 °C
3: 88 percent / KH / tetrahydrofuran / -78 °C
4: 68 percent / O3 / CH2Cl2 / -78 °C
View Scheme
参考文献
Demir, Ayhan S.; Enders, Dieter
Advanced Synthesis and Catalysis, 1997 , vol. 339, # 6 p. 553 - 563
反应条件
1: 88 percent / KH / tetrahydrofuran / -78 °C
2: 68 percent / O3 / CH2Cl2 / -78 °C
View Scheme
参考文献
Demir, Ayhan S.; Enders, Dieter
Advanced Synthesis and Catalysis, 1997 , vol. 339, # 6 p. 553 - 563
反应条件
potassium carbonate in acetone
13 h; Heating;
参考文献
Jacobson, Barry M.; Soteropoulos, Patricia; Bahadori, Sheila
Journal of Organic Chemistry, 1988 , vol. 53, # 14 p. 3247 - 3255
反应条件
chromium(VI) oxide in pyridine
参考文献
Barnier,J.-P.; Conia,J.-M.
Bulletin de la Societe Chimique de France, 1975 , p. 1654 - 1658
反应条件
sulfuric acid in benzene
参考文献
Lee-Ruff,E.; Khazanie,P.
Canadian Journal of Chemistry, 1975 , vol. 53, p. 1708 - 1713
反应条件
1: diethyl ether
2: LiAlH4 / diethyl ether
3: 1 h / 190 °C
4: CrO3 / pyridine
View Scheme
参考文献
Barnier,J.-P.; Conia,J.-M.
Bulletin de la Societe Chimique de France, 1975 , p. 1654 - 1658
