2,2’,4,4’,6,6’-六甲基二苯甲酮合成路线 (共 42 条)
反应条件
CO in pentane soln. of Cr(C6H2Me3)2(PMe3)2 in pentane is stirred under ambient pressure of CO for 30 min; filtn., soln. is cooled to -20°C, prisms of hexamethylbenzophenone form, elem. anal., (31)P-NMR;
参考文献
Organometallics, , vol. 7, p. 2372 - 2379
反应条件
in monofluoro-trichloromethane T=210 - 295°C; Activation energy; Further Variations:Solvents;
参考文献
Journal of the American Chemical Society, , vol. 123, # 11 p. 2618 - 2627
反应条件
sodium tetrahydroborate in N,N-dimethyl-formamide T=61°C; 60 h; other solvents; also in a presence of AIBN or m-DNB; also with NaBEt3H; Product distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 58, # 25 p. 7138 - 7142
反应条件
aluminium trichloride
参考文献
Journal of Molecular Structure, , vol. 193, p. 133 - 146
反应条件
T=20°C; P=44130.5 Torr;
参考文献
Journal of the American Chemical Society, , vol. 62, p. 1428,1431
反应条件
oxygen in benzene T=20°C; Kinetics;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 74, # 11 p. 2207 - 2218
反应条件
1: thionyl chloride 2: aluminum chloride View Scheme
参考文献
Journal of Molecular Structure, , vol. 193, p. 133 - 146
反应条件
diphosphoric acid tetrachloride 1) CH2Cl2, 40 deg C, 14 h, 2) CH2Cl2, 20 deg C, 4 h; Yield given. Multistep reaction;
参考文献
Chemische Berichte, , vol. 114, # 3 p. 926 - 936
参考文献
Zhurnal Obshchei Khimii, , vol. 16, p. 729,732,733
Chem. Zentralbl., , vol. 118, p. 1218
反应条件
48 h; Ambient temperature;
参考文献
Journal of Organometallic Chemistry, , vol. 336, p. C5 - C8