[(3'S,5'R,8'R,9'S,10'S,13'R,14'S,17'R)-4',4',10',13',14'-五甲基-17'-[(2R)-6-甲基庚烷-2-基]-11'-氧代-螺[1,3-二噻戊环-2,7'-2,3,5,6,8,9,12,15,16,17-十氢-1H-环戊并[a]菲]-3'-基]乙酸酯合成路线 （共 2 条）
→
56259-20-2[(3'S,5'R,8'R,9'S,10'S,13'R,14'S,17'R)-4',4',10',13',14'-五甲基-17'-[(2R)-6-甲基庚烷-2-基]-11'-氧代-螺[1,3-二噻戊环-2,7'-2,3,5,6,8,9,12,15,16,17-十氢-1H-环戊并[a]菲]-3'-基]乙酸酯
反应条件
hydrogenchloride; chloroform
参考文献
Voser et al.
Helvetica Chimica Acta, 1950 , vol. 33, p. 1893,1909
56259-20-2[(3'S,5'R,8'R,9'S,10'S,13'R,14'S,17'R)-4',4',10',13',14'-五甲基-17'-[(2R)-6-甲基庚烷-2-基]-11'-氧代-螺[1,3-二噻戊环-2,7'-2,3,5,6,8,9,12,15,16,17-十氢-1H-环戊并[a]菲]-3'-基]乙酸酯
→
反应条件
1: Raney nickel; dioxane
2: benzene; ethanolic KOH
3: CrO3; acetic acid
4: dioxane; amalgamated zinc; concentrated hydrochloric acid
View Scheme
参考文献
Voser et al.
Helvetica Chimica Acta, 1950 , vol. 33, p. 1893,1909
