2,3-二甲基-2-丁烯合成路线 （共 833 条）
反应条件
oxygen T=29.9 - 134.9°C; 0.5 h; Arrhenius parameters; Thermodynamic dataKineticsMechanism;
参考文献
Sway, Mohammed I.; Waddington, David J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1982 , p. 999 - 1004
反应条件
Ru(CO)4I2 T=160°C; 3 h; Sealed tube;
参考文献
BP OIL INTERNATIONAL LIMITED
Patent: EP1900714 A1, 2008 ;
Location in patent: Page/Page column 4-6 ;
参考文献
Banks,R.E. et al.
Journal of the Chemical Society [Section] C: Organic, 1971 , p. 2777 - 2785
反应条件
n-butyllithium; potassium tert-butylate in pentane
T=0°C; various concentrations of base; other metalating system; also with chlorotrimethylsilane as alkylating agent; Product distribution;
参考文献
Mills, Nancy S.; Rusinko, Andrew R.
Journal of Organic Chemistry, 1986 , vol. 51, # 13 p. 2567 - 2571
反应条件
hydrogen; [rhodium(I)(carbonyl)2(acetylacetonate)]; bis-2,6-(2,4-dimethylphenyl)-4-phenylphosphabenzene in toluene
T=100°C; P=45003.6 Torr; 24 h;
参考文献
Breit, Bernhard; Winde, Roland; Mackewitz, Thomas; Paciello, Rocco; Harms, Klaus
Chemistry - A European Journal, 2001 , vol. 7, # 14 p. 3106 - 3121
反应条件
1: zirconia/silica material; oxa-phospha-diphenylnorbornadienyl phosphonic acid / [Rh(acac)(CO)2] / toluene
2: zirconia/silica material; oxa-phospha-diphenylnorbornadienyl phosphonic acid; H2 / [Rh(acac)(CO)2] / toluene / 48 h / 110 °C / 22502.3 Torr
View Scheme
参考文献
Du Pont de Nemours and Co.
Patent: US2497303 , 1945 ;
参考文献
O'Brien, Brian A.; Lam, William Y.; DesMarteau, Darryl D.
Journal of Organic Chemistry, 1986 , vol. 51, # 23 p. 4466 - 4470
反应条件
ozone; pentane
T=-20°C;
参考文献
Murray, Robert W.; Kong, Wei; Rajadhyaksha, Shirish N.
Journal of Organic Chemistry, 1993 , vol. 58, # 2 p. 315 - 321
反应条件
ozone in hexane
T=0°C; Further byproducts given;
参考文献
Murray, Robert W.; Kong, Wei; Rajadhyaksha, Shirish N.
Journal of Organic Chemistry, 1993 , vol. 58, # 2 p. 315 - 321
反应条件
ozone; polyethylene
T=-78°C; 3 h; Title compound not separated from byproducts;
参考文献
Griesbaum, Karl; Volpp, Willi; Greinert, Reinhard; Greunig, Hans-Joachim; Schmid, Jurgen; Henke, Henning
Journal of Organic Chemistry, 1989 , vol. 54, # 2 p. 383 - 389
