2,3-二甲基-2-丁烯合成路线 （共 833 条）
反应条件
in toluene A pressure vessel is filled with a soln. of (C5Me5)Hf(C6H10)Cl in toluene and charged with 10 atm of H2, reaction mixture is stirred overnight at 70°C under N2.; Excess H2 is released, hot soln. is transferred into a Schlenk vessel, cooling of the soln. to room temp., a bright yellow ppt. is formed, solvent is decanted, ppt. is redissolved (hot toluene), slow cooling to -30°C, elem. anal.;
参考文献
Booij, Martin; Blenkers, Joop; Sinnema, Jacobus C. M.; Meetsma, Auke; Bolhuis, Fre van; Teuben, Jan H.
Organometallics, 1988 , vol. 7, p. 1029 - 1032
反应条件
diphenyl diselenide in chloroform-d1 T=20°C; 6 h; Inert atmosphereIrradiation;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 80, # 12 p. 2443 - 2445
反应条件
hydrogen T=425°C; P=760.051 Torr; Gas phase;
参考文献
Chemistry Letters, , vol. 41, # 8 p. 831 - 833
反应条件
C6Cl5OH; triethylaluminum; Ni(.beta.-C10H7CO2)2; tri-iso-propyl phosphine; isoprene in chlorobenzene T=20°C; 1 h; var. solvent, var. trialkylphosphine, var. diene, var. organoaluminum compd., var. time; Product distributionMechanism;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 66, # 10 p. 3069 - 3078
反应条件
boron trifluoride in diethyl ether T=25°C; 3 h;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2637 - 2642
参考文献
Industrial and Engineering Chemistry, , vol. 40, p. 1148
Zhurnal Obshchei Khimii, , vol. 16, p. 429
Chem.Abstr., , p. 684
反应条件
aluminium oxide-aluminium sulfate; boron trifluoride T=68°C;
反应条件
dirhodium tetraacetate in toluene 0.75 h; Heating;
参考文献
Martin, Michael G.; Ganem, Bruce
Tetrahedron Letters, 1984 , vol. 25, # 3 p. 251 - 254
反应条件
in hexane T=25°C; UV-irradiation; Quantum yield;
参考文献
Journal of the American Chemical Society, , vol. 123, # 22 p. 5188 - 5193
反应条件
quinoline; tricresyl phosphate in various solvent(s) Heating; Yield given. Yields of byproduct given;
参考文献
Synthesis, , # 10 p. 1300 - 1304
