2,3-二甲基-2-丁烯合成路线 （共 833 条）
反应条件
phenanthrene in acetonitrile
24 h; Irradiation;
参考文献
Borg, Robert M.; Arnold, Donald R.; Cameron, T. Stanley
Canadian Journal of Chemistry, 1984 , vol. 62, p. 1785 - 1802
反应条件
in acetonitrile
7 h; Irradiation; Further byproducts given. Yields of byproduct given;
参考文献
Lewis, Frederick D.; DeVoe, Robert J.
Tetrahedron, 1982 , vol. 38, # 8 p. 1069 - 1078
反应条件
in acetonitrile
24 h; Irradiationother photosensitors, other products; Product distribution;
参考文献
Borg, Robert M.; Arnold, Donald R.; Cameron, T. Stanley
Canadian Journal of Chemistry, 1984 , vol. 62, p. 1785 - 1802
反应条件
in acetonitrile
7 h; Irradiationvar. solvents and mixt. of solvents; effect of solvent polarity and light intensity; MechanismQuantum yield;
参考文献
Lewis, Frederick D.; DeVoe, Robert J.
Tetrahedron, 1982 , vol. 38, # 8 p. 1069 - 1078
反应条件
T=20°C; 16 h; Irradiationenergy barrier for 1,2-hydrogen migration, comparison of thermolysis (at 80 - 100 deg C) and photolysis, various temperatures; Product distributionMechanismKinetics;
参考文献
Liu, Michael T. H.; Subramanian, R.
Journal of Physical Chemistry, 1986 , vol. 90, # 1 p. 75 - 78
反应条件
T=20°C; 16 h; Irradiationenergy barrier for 1,2-hydrogen migration, comparison of thermolysis (at 80 - 100 deg C) and photolysis, various temperatures; Product distributionMechanismKinetics;
参考文献
Liu, Michael T. H.; Subramanian, R.
Journal of Physical Chemistry, 1986 , vol. 90, # 1 p. 75 - 78
反应条件
1: 89 percent / NBS, NaN3 / 1,2-dimethoxy-ethane; H2O / 2 h / 0 °C
2: 71 percent / PPh3, H2O / tetrahydrofuran / 24 h / Ambient temperature
View Scheme
参考文献
Lamaty,G.; Sivade,A.
Bulletin de la Societe Chimique de France, 1974 , p. 2149 - 2153
反应条件
1: With potassium tert-butylate in pentane
T=-60 - 0°C; Inert atmosphere;
2: With ammonium chloride in pentane
0.25 h;
3: With water
参考文献
Galy, Nicolas; Doucet, Henri; Santelli, Maurice
Tetrahedron Letters, 2010 , vol. 51, # 4 p. 695 - 697
反应条件
1: With potassium tert-butylate in pentane
T=-60 - 0°C;
2: With ammonium chloride in pentane
0.25 h;
3: With water
参考文献
Galy, Nicolas; Doucet, Henri; Santelli, Maurice
Tetrahedron Letters, 2010 , vol. 51, # 4 p. 695 - 697
反应条件
in chloroform-d1
PhotolysisInert atmosphere; Concentration;
参考文献
Raphael Karikachery, Alice; Lee, Han Baek; Masjedi, Mehdi; Ross, Andreas; Moody, Morgan A.; Cai, Xiaochen; Chui, Megan; Hoff, Carl D.; Sharp, Paul R.
Inorganic Chemistry, 2013 , vol. 52, # 7 p. 4113 - 4119
