2,3-二甲基-2-丁烯合成路线 (共 833 条)
反应条件
sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride in water
When a 1:1 mixture with 2,3-dimethylbut-2-ene was treated with a deficiency of bromoform under phase transfer conditions, a 1:26 mixture of cyclopropanated product (8) from the olefin and ethyl 4,4,4-tribromo-butanoate was formed.; Product distribution;
参考文献
Baird, Mark S.; Gerrard, Michele E.; Searle, Robert J. G.
Tetrahedron Letters, 1985 , vol. 26, # 51 p. 6353 - 6356
反应条件
IrradiationΔHT; Rate constantThermodynamic data;
参考文献
Liu, Michael T. H.; Soundararajan, N.; Paike, N.; Subramanian, R.
Journal of Organic Chemistry, 1987 , vol. 52, # 19 p. 4223 - 4227
反应条件
in 2,2,4-trimethylpentane
T=25°C; Rate constantMechanism;
参考文献
Moss; Yan; Krogh-Jespersen
Journal of the American Chemical Society, 1998 , vol. 120, # 5 p. 1088 - 1089
反应条件
acetic acid
T=0°C; Irradiation; Title compound not separated from byproducts;
参考文献
Liu, Michael T. H.; Chishti, Najmul H.; Tencer, Michael; Tomioka, Hideo; Izawa, Yasuji
Tetrahedron, 1984 , vol. 40, # 5 p. 887 - 892
反应条件
1: With potassium tert-butylate in pentane
T=-60 - 0°C; Inert atmosphere;
2: With ammonium chloride in pentane
0.25 h;
3: With water
参考文献
Galy, Nicolas; Doucet, Henri; Santelli, Maurice
Tetrahedron Letters, 2010 , vol. 51, # 4 p. 695 - 697
反应条件
1: With potassium tert-butylate in pentane
T=-60 - 0°C;
2: With ammonium chloride in pentane
0.25 h;
3: With water
参考文献
Galy, Nicolas; Doucet, Henri; Santelli, Maurice
Tetrahedron Letters, 2010 , vol. 51, # 4 p. 695 - 697
反应条件
in benzene
0.183333 h; Irradiation;
参考文献
Guy, Robert G.; Thompson, Jeffrey J.; White, Trevor J.
Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 44, p. 33 - 38
参考文献
Cauquis,G.; Pierre,G.
Tetrahedron, 1978 , vol. 34, p. 1475 - 1479
反应条件
(i) Br2, benzene, (ii) /BRN= 1361357/, 2,6-di-t-butyl-p-cresol; Multistep reaction;
参考文献
Bonnet,R. et al.
Tetrahedron, 1976 , vol. 32, p. 2439 - 2444
反应条件
in benzene
0.183333 h; Irradiation;
参考文献
Guy, Robert G.; Thompson, Jeffrey J.; White, Trevor J.
Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 44, p. 33 - 38