2-二环己基磷-2,4,6-三异丙基联苯合成路线 （共 3 条）
反应条件
1: 2-bromo-1,3,5-triisopropylbenzene With magnesium; ethylene dibromide in tetrahydrofuran T=65°C; 1 h; 2: 1-bromo-2-chloro-benzene in tetrahydrofuran T=65°C; 1 h; 3: chloro-dicyclohexylphosphine With copper(l) chloride in tetrahydrofuran T=20°C; 20 h;
参考文献
Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan
Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831
反应条件
1: 2-bromo-1,3,5-triisopropylbenzene With magnesium; ethylene dibromide in tetrahydrofuran T=65°C; Inert atmosphere; 2: 1-bromo-2-chloro-benzene in tetrahydrofuran T=65°C; 2 h; 3: dicyclohexylbromophosphine With copper(l) chloride in tetrahydrofuran T=20°C; 10 h; Inert atmosphere;
参考文献
Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan
Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831
反应条件
[RuCl2(cod)]n in 1,4-dioxane
T=120°C; 48 h; Inert atmosphere;
参考文献
Ackermann, Lutz; Kozhushkov, Sergei I.; Yufit, Dmitry S.
Chemistry - A European Journal, 2012 , vol. 18, # 38 p. 12068 - 12077
