potassium phosphate; Pd((CH3)2C6H3NC(CH3)CHC(CH3)NC6H3(CH3)2)(CH3)(P(CH2CH3)3); tetrabutylammomium bromide in water; N,N-dimethyl-formamide T=100°C; Heck coupling; 8 h; optical yield given as percent destereoselective reaction;

dichloro-acetic acid; benzhydroxamic acid chloride in chloroform T=40°C; KineticsProduct distribution; Further Variations:Reagents;

dichloro-acetic acid in chloroform T=40°C; 0.916667 h; ΔH(excit.); ΔS(excit.); ΔG(excit.); Thermodynamic dataRate constantMechanism;

in tetrahydrofuran

sodium hydrogencarbonate influence of the solvents on yield of σ-substutution by various N-haloimides; Mechanism;

acetic acid in dichloromethane also in presence of HCl or without acid; Product distribution;