2,4-二甲基-3-戊酮合成路线 (共 349 条)
反应条件
und beim Behandeln des entstehenden Natriumverbindung mit Methyljodid in Benzol;
参考文献
Haller; Bauer
Annales de Chimie (Cachan, France), 1924 , vol. <10>1, p. 292
参考文献
Louw, Robert; Vermeeren, Hans P.W.; Vogelzang, Martijn W.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1875 - 1880
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; Sm(OTf)2 1.) THF, cyclohexane, RT, 1 h, 2.) THF, cyclohexane, RT, 0.5 h; Yield given. Multistep reaction;
参考文献
Fukuzawa, Shin-ichi; Tsuchimoto, Teruhisa; Kanai, Takeshi
Chemistry Letters, 1994 , # 11 p. 1981 - 1984
反应条件
in diethyl ether 0.5 h; Ambient temperature;
参考文献
Green, Iain G.; Roberts, Brian P.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 1597 - 1606
参考文献
Stas
Bulletin des Societes Chimiques Belges, 1926 , vol. 35, p. 382
Chem. Zentralbl., 1927 , vol. 98, # I p. 715
反应条件
oxygen in decane T=49.9 - 99.9°C; Irradiationtime interval - 900-7200 s; Product distributionMechanismKinetics;
参考文献
Costello, Andrew R.; Lindsay Smith, John R.; Waddington, David J.
International Journal of Chemical Kinetics, 1996 , vol. 28, # 3 p. 201 - 215
反应条件
in decane T=49.9 - 99.9°C; Irradiationtime interval - 900-7200 s; Product distributionMechanismKinetics;
参考文献
Heller; Gordon
Journal of Physical Chemistry, 1956 , vol. 60, p. 1315
反应条件
in n-heptane T=0 - 90°C; Irradiationfurther solvents; Product distribution;
参考文献
Lipscher, Juraj; Fischer, Hanns
Journal of Physical Chemistry, 1984 , vol. 88, # 12 p. 2555 - 2559
反应条件
in acetone Heating; Yields of byproduct given;
参考文献
Singh, Megh; Murray, Robert W.
Journal of Organic Chemistry, 1992 , vol. 57, # 15 p. 4263 - 4270
反应条件
1: 1.) N2H4*H2O, 2.) I2, Et3N / 1.) ethanol, reflux, 1 h, 2.) THF, room temperature, 1 h 2: 16 percent Chromat. / methanol / 4 h / Irradiation View Scheme
参考文献
Freeman, Peter K.; Wuerch, Stephen E.; Clapp, Gary E.
Journal of Organic Chemistry, 1990 , vol. 55, # 9 p. 2587 - 2590