三噻吩并[3',4':3,4;3'',4'':5,6;3''',4''':7,8]环辛四烯并[1,2-c]噻吩合成路线 （共 3 条）
反应条件
[2,2']bipyridinyl; (Z,Z)-1,5-cyclooctadiene; bis(1,5-cyclooctadiene)nickel (0) in N,N-dimethyl-formamide
参考文献
Patra, Asit; Wijsboom, Yair H.; Shimon, Linda J. W.; Bendikov, Michael
Angewandte Chemie - International Edition, 2007 , vol. 46, # 46 p. 8814 - 8818
反应条件
[2,2']bipyridinyl; bis(1,5-cyclooctadiene)nickel (0) in N,N-dimethyl-formamide
T=70°C; 22 h;
参考文献
Zhou, Zhen-hua; Yamamoto, Takakazu
Journal of Organometallic Chemistry, 1991 , vol. 414, # 1 p. 119 - 127
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; Metallation; 2 h;
2: With zinc(II) chloride in tetrahydrofuran; hexane
T=-50°C; Substitution; 2 h;
3: With copper dichloride in tetrahydrofuran; hexane
T=-78°C; Cyclization; 2 h;
参考文献
Kabir, S. M. Humayun; Miura, Mami; Sasaki, Shigeru; Harada, Genta; Kuwatani, Yoshiyuki; Yoshida, Masato; Iyoda, Masahiko
Heterocycles, 2000 , vol. 52, # 2 p. 761 - 774
