5A-孕烷-3A,20A-二醇合成路线 (共 26 条)
反应条件
dimethylsulfide borane complex; (S)-1-phenyl-2-hydroxyethylamine in tetrahydrofuran 0.4 h; Ambient temperature;
参考文献
Goendoes, Gyoergy; Orr, James C.
Liebigs Annalen der Chemie, 1993 , # 5 p. 581 - 582
反应条件
ethanol; platinum Hydrogenation;
参考文献
US2352852 , ;
Journal of the American Chemical Society, , vol. 62, p. 516
参考文献
Journal of the American Chemical Society, , vol. 73, p. 2283,2285
参考文献
Journal of the American Chemical Society, , vol. 59, p. 2291,2296
反应条件
1: platinum; acetic acid / Hydrogenation 2: methanol. HCl View Scheme
参考文献
Journal of the American Chemical Society, , vol. 73, p. 2283,2285
反应条件
1: CrO3; acetic acid / Behandeln des Reaktionsprodukts in Aether mit wss. NaOH 2: ethanol; platinum / Hydrogenation View Scheme
参考文献
Journal of the American Chemical Society, , vol. 62, p. 516
反应条件
ethanol; platinum Hydrogenation;
参考文献
Journal of the American Chemical Society, , vol. 61, p. 586
反应条件
recombinant human aldo-keto reductase 1C3; NADPH in methanol T=37°C; pH=7; 1.5 h; aq. phosphate bufferEnzymatic reaction; stereospecific reaction;
参考文献
Biochemical Journal, , vol. 437, # 1 p. 53 - 61
反应条件
1: 391 mg / NaH / dimethylsulfoxide / 5 h / 60 °C 2: 1.) NaBH4, BF3*Et2O; 2.) 10percent NaOH, 30percent H2O2 / 1.) diglyme, r.t., 1 h; 2.) 35 deg C, r.t., 1 h View Scheme
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 31, # 11 p. 3819 - 3828
反应条件
tetrahydrofuran; lithium aluminium tetrahydride
参考文献
Journal of the Chemical Society, , p. 1218,1220