顺式-11-十六烯-1-醇合成路线 （共 65 条）
反应条件
pyridinium p-toluenesulfonate in methanol T=55°C; 6 h;
参考文献
Trehan; Vig; Singh; Sharma; Kad
Indian Journal of Chemistry - Section B Organic Chemistry Including Medicinal Chemistry, 1990 , vol. 29, # 6 p. 518 - 520
反应条件
bis(cyclopentadienyl)titanium dichloride; 2-methylpropylmagnesium bromide
参考文献
Ishmuratov; Ishmuratova; Odinokov; Tolstikov
Chemistry of Natural Compounds, 1997 , vol. 33, # 1 p. 25 - 30
反应条件
C32H41N3O4Ru in tetrahydrofuran T=20°C; Inert atmosphereGlovebox; chemoselective reaction;
参考文献
Herbert, Myles B.; Marx, Vanessa M.; Pederson, Richard L.; Grubbs, Robert H.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 1 p. 310 - 314
Angew. Chem., 2012 , vol. 125, # 1 p. 328 - 332,5
反应条件
sodium tetrahydroborate in methanol T=0°C; 2 h;
参考文献
Dhillon, Ranjit S.; Singh, Jasvinder
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 757 - 759
反应条件
lithium aluminium tetrahydride in diethyl ether 5 h;
参考文献
Singh; Misra
Journal of the Indian Chemical Society, 1990 , vol. 67, # 7 p. 565 - 567
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Seidel, Wolfgang; Schaefer, Hans J.
Chemische Berichte, 1980 , vol. 113, # 12 p. 3898 - 3903
反应条件
sodium hydroxide in ethanol 1 h; Heating;
参考文献
Brown, Herbert C.; Wang, Kung K.
Journal of Organic Chemistry, 1986 , vol. 51, # 24 p. 4514 - 4517
反应条件
1: 1.) lithium amide / 1.) HMPTA, RT, 1.5 h, 2.) HMPTA, 25 deg C, 8 h 2: 91 percent / NaBH4, diethylamine, Ni(CH3CO2)4H2O, hydrogen / ethanol View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 27, # 4.1 p. 621 - 624
Zhurnal Organicheskoi Khimii, , vol. 27, # 4 p. 722 - 727
反应条件
1: HMPA / tetrahydrofuran 2: p-toluenesulfonic acid / methanol 3: H2 / Pd/BaSO4 View Scheme
参考文献
Pesticide Science, , vol. 41, # 2 p. 97 - 103
反应条件
1: p-toluenesulfonic acid / methanol 2: H2 / Pd/BaSO4 View Scheme
参考文献
Pesticide Science, , vol. 41, # 2 p. 97 - 103
反应条件
1: ethylmagnesium bromide / diethyl ether / 3.5 h / Heating 2: diethyl ether / 4 h / 0 - 2 °C 3: 79 percent / pyridine / 1.) -5 deg C, 6 h; 2.) 0 deg C, 12 h 4: 53 percent / sodium iodide, zinc dust / tetrahydrofuran / 1.) 65-70 deg C, 3 h; 2.) 20 deg C, 3 h 5: 1.) 2percent O3 in O2; 2.) sodium tetrahydroborate / 1.) cyclohexane, methanol; 2.) room temp., 15 h 6: 1.) isobutylmagnesium bromide; 2.) C5H5TiCl2 / 1.) diethyl ether, 0 deg C, 15 min; 2.) room temp., 1-1,5 h View Scheme
参考文献
Chemistry of Natural Compounds, , vol. 23, # 3 p. 365 - 368
Khimiya Prirodnykh Soedinenii, , # 3 p. 440 - 444
