4,4,14,14-四乙氧基-3,15-二氧杂-8,9,10-三硫杂-4,14-二硅杂十七烷合成路线 （共 9 条）
反应条件
hydrogen; T-8027 (52percent Ni, doped with 2.4percent zirconium) in ethanol
T=159°C; P=37503.8 Torr; 2.2 h; Product distribution / selectivity;
参考文献
Degussa AG
Patent: US2006/252952 A1, 2006 ;
Location in patent: Page/Page column 7-9 ;
反应条件
NaHS monohydrate; sodium carbonate; sulfur; sodium hydroxide in ethanol; water
T=55 - 80°C; Product distribution / selectivity;
参考文献
Korth, Karsten; Kiefer, Ingo; Alig, Alfred; Deschler, Ulrich; Droege, Helmut; Koenigstein, Sefan; Schwan, Stephanie
Patent: US2010/29971 A1, 2010 ;
Location in patent: Page/Page column 9-10 ;
反应条件
sodium sulfide; tetrabutylammomium bromide; sulfur in water
T=80 - 90°C; 5.66667 h; Product distribution / selectivity;
参考文献
Shin-Etsu Chemical Co., Ltd.
Patent: US2006/106240 A1, 2006 ;
Location in patent: Page/Page column 4 ;
反应条件
NaHS monohydrate; sodium carbonate; sulfur; sodium hydroxide in ethanol; water
T=65 - 75°C; Product distribution / selectivity;
参考文献
Korth, Karsten; Kiefer, Ingo; Alig, Alfred; Deschler, Ulrich; Droege, Helmut; Koenigstein, Sefan; Schwan, Stephanie
Patent: US2010/29971 A1, 2010 ;
Location in patent: Page/Page column 10 ;
反应条件
1: With sulfur in toluene
T=80°C;
2: With tetrabutylammomium bromide; sulfur in water; toluene
T=80 - 85°C; 5.58333 h; Product distribution / selectivity;
参考文献
Shin-Etsu Chemical Co., Ltd.
Patent: US2006/106240 A1, 2006 ;
Location in patent: Page/Page column 4-5 ;
反应条件
1: With sulfur
T=80°C;
2: With Na2S3; tetrabutylammomium bromide in water
T=80 - 90°C; 3.66667 h; Product distribution / selectivity;
参考文献
Shin-Etsu Chemical Co., Ltd.
Patent: US2006/106240 A1, 2006 ;
Location in patent: Page/Page column 4 ;
反应条件
1: 4,4,13,13-tetraethoxy-3,14-dioxa-8,9-dithia-4,13-disilahexadecane With sodium in toluene
T=110°C; 0.75 - 1.15 h;
2: octanoic acid chloride in toluene
T=45 - 60°C; 1 - 2 h;
3: With water in toluene
T=45°C; Product distribution / selectivity;
参考文献
General Electric Company
Patent: US6777569 B1, 2004 ;
Location in patent: Page column 7-9 ;
反应条件
1: TESPT With sodium in Solventreg; 140
T=110°C; 0.75 h;
2: octanoic acid chloride in Solventreg; 140
T=45 - 104°C; 1 h;
3: With water in toluene
T=45°C; Product distribution / selectivity;
参考文献
General Electric Company
Patent: US6777569 B1, 2004 ;
Location in patent: Page column 9 ;
反应条件
sodium oligosulfide in ethylene glycol dimethyl ether
1 h; Heating; Further byproducts given;
参考文献
Yamada, Nobuo; Furukawa, Mutsuhisa; Nishi, Masayuki; Takata, Toshikazu
Chemistry Letters, 2002 , # 4 p. 454 - 455
