1H,1H,2H-全氟辛醛合成路线 （共 19 条）
反应条件
(i) (irradiation), (ii) acid; Multistep reaction;
参考文献
Cantacuzene,D.; Dorme,R.
Tetrahedron Letters, 1975 , p. 2031 - 2034
反应条件
sodium dithionite; water; sodium carbonate in tetrahydrofuran
T=5°C; 5 h; Reagent/catalyst;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY; MOLOY, Kenneth, Gene; PENG, Sheng
Patent: WO2014/89260 A1, 2014 ;
Location in patent: Page/Page column 11 ;
反应条件
sodium dithionite; sodium carbonate in tetrahydrofuran; water
T=5°C; 5 h;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY; MOLOY, Kenneth, Gene; PENG, Sheng
Patent: WO2014/89260 A1, 2014 ;
Location in patent: Page/Page column 12-13 ;
反应条件
sodium dithionite; water; sodium carbonate in tetrahydrofuran
T=5°C; 5 h;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY; MOLOY, Kenneth, Gene; PENG, Sheng
Patent: WO2014/89260 A1, 2014 ;
Location in patent: Page/Page column 14 ;
反应条件
sodium dithionite; water; sodium carbonate in tetrahydrofuran
T=5°C; 5 h;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY; MOLOY, Kenneth, Gene; PENG, Sheng
Patent: WO2014/89260 A1, 2014 ;
Location in patent: Page/Page column 15 ;
反应条件
N-bromosuccinmide in water; acetonitrile
0.166667 h;
参考文献
Uneyama, Kenji; Kitagawa, Kouichi
Tetrahedron Letters, 1991 , vol. 32, # 28 p. 3385 - 3386
反应条件
1: azobisisobutyronitrile / 0.67 h / 80 °C
2: 15percent H2SO4, H2O / 3 h / Heating
View Scheme
参考文献
Napoli, M.; Scipioni, A.; Conte, L.; Legnaro, E.; Krotz, L. N.
Journal of Fluorine Chemistry, 1994 , vol. 66, # 3 p. 249 - 252
反应条件
2-methyl-but-3-yn-2-ol in neat (no solvent)
T=80°C; 12 h;
参考文献
Laurent; Blancou; Commeyras
Tetrahedron Letters, 1992 , vol. 33, # 18 p. 2489 - 2492
反应条件
acrylic acid in various solvent(s)
T=80°C; 12 h;
参考文献
Laurent; Blancou; Commeyras
Tetrahedron Letters, 1992 , vol. 33, # 18 p. 2489 - 2492
反应条件
potassium hydroxide in methanol
T=60°C; 2 h; Title compound not separated from byproducts;
参考文献
Laurent; Blancou; Commeyras
Tetrahedron Letters, 1992 , vol. 33, # 18 p. 2489 - 2492
