1,3,4,6-O-四乙酰基-2-叠氮-2-脱氧-alpha-D-吡喃葡萄糖合成路线 （共 8 条）
反应条件
pyridine; 4-(N,N-dimethlyamino)pyridine; copper(II) sulfate
参考文献
US2011/201801 A1, ;
Page/Page column 22 ;
反应条件
in acetic acid T=100°C; 1 h;
参考文献
Saxon, Eliana; Luchansky, Sarah J.; Hang, Howard C.; Yu, Chong; Lee, Sandy C.; Bertozzi, Carolyn R.
Journal of the American Chemical Society, 2002 , vol. 124, # 50 p. 14893 - 14902
反应条件
1: TfN3; aq. CuSO4; K2CO3 / methanol / 24 h / 20 °C 2: DMAP; pyridine / 12 h / 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 9, # 1 p. 140 - 169
反应条件
1: 3,4,6-tri-O-acetyl-D-glucal With sodium azide; ammonium cerium(IV) nitrate in acetonitrile T=20°C; 24 h; 2: sodium acetate With acetic acid T=100°C; 2 h;
参考文献
Zhang, Gui-Sheng; Chen, Jie; Min, Ji-Mei; Zhang, Li-He
Helvetica Chimica Acta, 2003 , vol. 86, # 6 p. 2073 - 2081
反应条件
pyridine; 4-(N,N-dimethlyamino)pyridine T=20°C; 12 h;
参考文献
Orgueira, Hernan A.; Bartolozzi, Alessandra; Schell, Peter; Litjens, Remy E. J. N.; Palmacci, Emma R.; Seeberger, Peter H.
Chemistry - A European Journal, 2003 , vol. 9, # 1 p. 140 - 169
反应条件
azido chloride in tetrachloromethane T=0°C; 1 h; Irradiationother halogen-azide, in other solvents under irradiation or in the dark, various time and temperature; Product distribution;
参考文献
Carbohydrate Research, , vol. 98, p. 25 - 36
反应条件
[Au(PPh3)]NTf2 T=25°C; 2 h; Overall yield = 36 percent;
参考文献
Journal of the American Chemical Society, , vol. 135, # 49 p. 18396 - 18405
反应条件
sodium azide; ammonium cerium(IV) nitrate 1.) EtOAc, CH3CN, -40 deg C, 6 d; 2.) glacial acetic acid, 100 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Carbohydrate Research, , vol. 136, p. 153 - 176
