hydrogen cation in water
Kinetics; byproducts: Br(1-); oxidation of SCN(1-) by BrO3(1-) in acidic soln.; various conditions; mechanism discussed;;
参考文献
Radhakrishnamurti, P. S.; Misra, S. A.; Panda, J. K.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1981 , vol. 20, # 5 p. 459 - 461
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sodium perchlorate in water
Kinetics; Irradiation (UV/VIS); irradn. at 365 nm in quartz reactor at 25°C; ionic strength was maintained with aq. NaClO4 (pH 4); not isolated, monitoring by UV;
参考文献
Ali; Madjid
Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2000 , vol. 39, # 11 p. 1164 - 1168
Domenico et al.
Journal of Chemical Physics, 1971 , vol. 54, p. 4460
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Gmelin Handbook: C: MVol.D3, 6.2.4.7.4, page 205 - 205
in gas; solid
Kinetics; byproducts: HCN(1-); C was irradiated at room temp. and pressure <1*E(-10) Torr by 800 eV N2+ions with a dose of (1-1.5)*E+18 ions/cm2, then heated up to 1200.degre e.C; by masspectrometry;
参考文献
Deng; Souda
Journal of Chemical Physics, 2002 , vol. 116, # 4 p. 1725 - 1730
carbon
byproducts: CO, CO2, N2; investigation of reduction of NO on the C-covered Rh(331) surface at different temperatures >400K; discussion of mechanism;; not isolated, detected by XPS and SIMS;;
参考文献
DeLouise, L. A.; Winograd, N.
Surface Science, 1985 , vol. 154, p. 79 - 89
perchloric acid in water
Kinetics; oscillatory reaction; flow experiments (continously stirred tank reactor or batch react., 25+/-0.1°C, excess of BrO3(1-);; not isolated, followed by redox potential or absorption measurements;;
参考文献
Simoyi, Reuben H.
Journal of Physical Chemistry, 1987 , vol. 91, # 6 p. 1557 - 1561
